Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
3. One atom of hydrogen in acetic acid (HC_{2}H_{3}O_{2})[6] may be
replaced by the basic radical ammonium (NH_{4}), producing the salt
ammonium acetate (NH_{4}C_{2}H_{3}O_{2}).
[Footnote 6: Symbols indicating the number of atoms of replaceable
hydrogen occupy the foremost position in the formulæ of acids, as shown in
the text.]
Acids which, like those mentioned in the foregoing examples, contain one
atom of replaceable hydrogen are called monobasic; those which contain two
such atoms (_e.g._ sulphuric acid, H_{2}SO_{4}; tartaric acid,
H_{2}C_{4}H_{4}O_{6}),[7] dibasic; those which contain three such atoms
(_e.g._ phosphoric acid, H_{3}PO_{4}; citric acid,
H_{3}C_{6}H_{5}O_{7}),[7] tribasic; and so on with acids of higher
basicity. Acids of greater basicity than unity are frequently termed
polybasic.
[Footnote 7: See footnote, p. 26.]
Besides containing replaceable or basic hydrogen, acids are further
characterised by the property of combining with alkaloids to form salts;
_e.g._——
Sulphuric Acid. Quinia.
H_{2}SO_{4} + 2C_{24}H_{24}N_{2}O_{2} =
Quinia Sulphate.
(C_{20}H_{24}N_{2}O_{2})_{2} . H_{2}SO_{4}
Acetic Acid. Morphia.
HC_{2}H_{3}O_{2} + C_{17}H_{19}NO_{3} =
Morphia Acetate.
C_{17}H_{19}NO_{3} . HC_{2}H_{3}O_{2}
=Dibasic Acids.= See ACID.
=Fatty Acids.= Acids separable from fats or oils; _e.g._ stearic acid,
oleic acid, butyric acid, &c.
=Inorganic Acids.= Same as MINERAL ACIDS (which _see_).
=Mineral Acids.= Acids chiefly or wholly derived from the mineral kingdom.
In _medicine_, sulphuric, hydrochloric, and nitric acids, are commonly so
called.
=Monobasic Acids.= See ACID.
=Organic Acids.= Acids formed by, or derived from organic substances;
_e.g._ acetic acid, tartaric acid, uric acid, &c.
=Polybasic Acids.= See ACID.
=Pyro-acids.= Acids resulting from the decomposition by heat of other
acids, _e.g._ gallic acid, when heated, yields pyro-gallic acid.
=Tribasic Acids.= See ACID.
=ACIDIFICA′TION.= [Eng., Fr.] _Syn._ ACIDIFICA′TIO, L. In _chemistry_, the
act, process, or state of acidifying, or of making, becoming, or
impregnated with acid.
=ACIDIM′ETER.= _Syn._ ACIDOM′ETER; ACIDIME′TRUM, &c., L.; ACIDIMÈTRE, Fr.
An instrument or apparatus employed in acidimetry.
The ordinary acidimeters of the chemist are small tubes, constructed to
hold exactly 1000 grains of distilled water, at 60° Fahr., within the
limits of their scale, which is accurately graduated into 100 divisions.
They are used to contain the alkaline solutions (TEST-LIQUORS, NORMAL or
STANDARD SOLUTIONS) employed in the following processes.
Beaumé’s Acidimeter, and others of the same class, are HYDROMETERS, and
are described under that ‘head.’
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