Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Or, since the equivalent of the test-liquid is 100, it will bear the same
proportion to the equiv. of the acid examined as the number of the
acidimeter divisions of the test-liquid consumed in neutralising 100 gr.,
do to the per-centage sought. Thus:——50 gr. of hydrochloric acid take 45
acidimeter divisions to effect neutralisation, what is its real
strength?——The equiv. of hydrochloric acid is 36·5: therefore——
100 : 36·5 :: 45 : 16·425%
and, since only 50 gr. (instead of 100 gr.) were examined——
16·425 × 2 = 32·85%
Some operators prefer employing 100 gr. instead of the equivalent weights
of the given tests in making their test-solutions, in which case each gr.
or 1000th part represents 1/10th, and each acidimeter degree 1 gr. of the
alkali or carbonate employed; when a similar proportion will obtain to
that first above given.
In technical analysis it is more convenient if the number of acidimeter
divisions of the ‘test-liquid’ consumed express the per-centage strength
of the acid, without further calculation. For this purpose the number of
grains of the acid taken for the assay should correspond to the equivalent
number of such acid (see _Table_ I, below); or to some convenient aliquot
part of it, as the 1/2, 1/4, 1/5, or 1/10th; the per-centage answer, in
the last case, being doubled, quadrupled, &c., according to the aliquot
part taken. The reason of this is obvious.
For the test-solutions, ammonia, and the dry and crystallised carbonates
and bicarbonates of potash and soda, are used, and are made by dissolving
in water their constituents except ammonia, of which 1000 grains, or one
litre, of solution of specific gravity 0·992 contains exactly one
equivalent.
53 grains (or grammes) of pure anhydrous carbonate of soda, prepared by
gradually heating to redness the crystallised salt, constitute one
equivalent (half the atomic weight), and 69 grains (or grammes) of pure
dry carbonate of potash. Of the crystallised salt 143 grains of carbonate
of soda will be required, and 84 grains (grammes) of the crystallised
bicarbonate of soda, and 100 of the crystallised bicarbonate of potash.
Occasionally solutions containing in one thousand parts, 50 of pure
carbonate of lime or chalk, or 28 of pure caustic lime, are used.
Besides these, a process known as Kiefer’s is practised, and an ammoniacal
solution of oxide of copper is employed as the ‘test-liquor,’ and the
‘point of neutralisation’ is known by the turbidity observed as soon as
the free acid present is completely saturated.
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