CHATHAM ISLAND. _Craters composed of a singular kind of tuff._—Towards the eastern end of this island there occur two craters composed of two kinds of tuff; one kind being friable, like slightly consolidated ashes; and the other compact, and of a different nature from anything which I have met with described. This latter substance, where it is best characterised, is of a yellowish-brown colour, translucent, and with a lustre somewhat resembling resin; it is brittle, with an angular, rough, and very irregular fracture, sometimes, however, being slightly granular, and even obscurely crystalline: it can readily be scratched with a knife, yet some points are hard enough just to mark common glass; it fuses with ease into a blackish-green glass. The mass contains numerous broken crystals of olivine and augite, and small particles of black and brown scoriæ; it is often traversed by thin seams of calcareous matter. It generally affects a nodular or concretionary structure. In a hand specimen, this substance would certainly be mistaken for a pale and peculiar variety of pitchstone; but when seen in mass its stratification, and the numerous layers of fragments of basalt, both angular and rounded, at once render its subaqueous origin evident. An examination of a series of specimens shows that this resin-like substance results from a chemical change on small particles of pale and dark-coloured scoriaceous rocks; and this change could be distinctly traced in different stages round the edges of even the same particle. The position near the coast of all the craters composed of this kind of tuff or peperino, and their breached condition, renders it probable that they were all formed when standing immersed in the sea; considering this circumstance, together with the remarkable absence of large beds of ashes in the whole archipelago, I think it highly probable that much the greater part of the tuff has originated from the trituration of fragments of the grey, basaltic lavas in the mouths of craters standing in the sea. It may be asked whether the heated water within these craters has produced this singular change in the small scoriaceous particles and given to them their translucent, resin-like fracture. Or has the associated lime played any part in this change? I ask these questions from having found at St. Jago, in the Cape de Verde Islands, that where a great stream of molten lava has flowed over a calcareous bottom into the sea, the outermost film, which in other parts resembles pitchstone, is changed, apparently by its contact with the carbonate of lime, into a resin-like substance, precisely like the best characterised specimens of the tuff from this archipelago.[2]