Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The first step in the making of alcohol is to change the starch over
into sugar. This transformation is effected in the natural course of
sprouting by which the insoluble starch stored up in the seed is
converted into the soluble glucose for the sap of the growing plant.
This malting process is that mainly made use of in the production of
alcohol from grain. But there are other ways of effecting the change. It
may be done by heating with acid as we have seen, or according to a
method now being developed the final conversion may be accomplished by
mold instead of malt. In applying this method, known as the amylo
process, to corn, the meal is mixed with twice its weight of water,
acidified with hydrochloric acid and steamed. The mash is then cooled
down somewhat, diluted with sterilized water and innoculated with the
mucor filaments. As the mash molds the starch is gradually changed over
to glucose and if this is the product desired the process may be stopped
at this point. But if alcohol is wanted yeast is added to ferment the
sugar. By keeping it alkaline and treating with the proper bacteria a
high yield of glycerin can be obtained.
In the fermentation process for making alcoholic liquors a little
glycerin is produced as a by-product. Glycerin, otherwise called
glycerol, is intermediate between sugar and alcohol. Its molecule
contains three carbon atoms, while glucose has six and alcohol two. It
is possible to increase the yield of glycerin if desired by varying the
form of fermentation. This was desired most earnestly in Germany during
the war, for the British blockade shut off the importation of the fats
and oils from which the Germans extracted the glycerin for their
nitroglycerin. Under pressure of this necessity they worked out a
process of getting glycerin in quantity from sugar and, news of this
being brought to this country by Dr. Alonzo Taylor, the United States
Treasury Department set up a special laboratory to work out this
problem. John R. Eoff and other chemists working in this laboratory
succeeded in getting a yield of twenty per cent. of glycerin by
fermenting black strap molasses or other syrup with California wine
yeast. During the fermentation it is necessary to neutralize the acetic
acid formed with sodium or calcium carbonate. It was estimated that
glycerin could be made from waste sugars at about a quarter of its
war-time cost, but it is doubtful whether the process would be
profitable at normal prices.
We can, if we like, dispense with either yeast or bacteria in the
production of glycerin. Glucose syrup suspended in oil under steam
pressure with finely divided nickel as a catalyst and treated with
nascent hydrogen will take up the hydrogen and be converted into
glycerin. But the yield is poor and the process expensive.
Public-domain text, read in full here on John Shaqi.
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