Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Northern nations are accustomed to hard fats and do not take to oils for
cooking or table use as do the southerners. Butter and lard are
preferred to olive oil and ghee. But this does not rule out cottonseed.
It can be combined with the hard fats of animal or vegetable origin in
margarine or it may itself be hardened by hydrogen.
To understand this interesting reaction which is profoundly affecting
international relations it will be necessary to dip into the chemistry
of the subject. Here are the symbols of the chief ingredients of the
fats and oils. Please look at them.
Linoleic acid C_{18}H_{32}O_{2}
Oleic acid C_{18}H_{34}O_{2}
Stearic acid C_{18}H_{36}O_{2}
Don't skip these because you have not studied chemistry. That's why I am
giving them to you. If you had studied chemistry you would know them
without my telling. Just examine them and you will discover the secret.
You will see that all three are composed of the same elements, carbon,
hydrogen, and oxygen. Notice next the number of atoms in each element as
indicated by the little low figures on the right of each letter. You
observe that all three contain the same number of atoms of carbon and
oxygen but differ in the amount of hydrogen. This trifling difference in
composition makes a great difference in behavior. The less the hydrogen
the lower the melting point. Or to say the same thing in other words,
fatty substances low in hydrogen are apt to be liquids and those with a
full complement of hydrogen atoms are apt to be solids at the ordinary
temperature of the air. It is common to call the former "oils" and the
latter "fats," but that implies too great a dissimilarity, for the
distinction depends on whether we are living in the tropics or the
arctic. It is better, therefore, to lump them all together and call
them "soft fats" and "hard fats," respectively.
Fats of the third order, the stearic group, are called "saturated"
because they have taken up all the hydrogen they can hold. Fats of the
other two groups are called "unsaturated." The first, which have the
least hydrogen, are the most eager for more. If hydrogen is not handy
they will take up other things, for instance oxygen. Linseed oil, which
consists largely, as the name implies, of linoleic acid, will absorb
oxygen on exposure to the air and become hard. That is why it is used in
painting. Such oils are called "drying" oils, although the hardening
process is not really drying, since they contain no water, but is
oxidation. The "semi-drying oils," those that will harden somewhat on
exposure to the air, include the oils of cottonseed, corn, sesame, soy
bean and castor bean. Olive oil and peanut oil are "non-drying" and
contain oleic compounds (olein). The hard fats, such as stearin,
palmitin and margarin, are mostly of animal origin, tallow and lard,
though coconut and palm oil contain a large proportion of such saturated
compounds.
Public-domain text, read in full here on John Shaqi.
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