Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The early metallurgist had no hotter a fire than he could make by
blowing charcoal with a bellows. This was barely enough for the smelting
of iron. But by the bringing of two carbon rods together, as in the
electric arc light, we can get enough heat to volatilize the carbon at
the tips, and this means over 7000 degrees Fahrenheit. By putting a
pressure of twenty atmospheres onto the arc light we can raise it to
perhaps 14,000 degrees, which is 3000 degrees hotter than the sun. This
gives the modern man a working range of about 14,500 degrees, so it is
no wonder that he can perform miracles.
When a builder wants to make an old house over into a new one he takes
it apart brick by brick and stone by stone, then he puts them together
in such new fashion as he likes. The electric furnace enables the
chemist to take his materials apart in the same way. As the temperature
rises the chemical and physical forces that hold a body together
gradually weaken. First the solid loosens up and becomes a liquid, then
this breaks bonds and becomes a gas. Compounds break up into their
elements. The elemental molecules break up into their component atoms
and finally these begin to throw off corpuscles of negative electricity
eighteen hundred times smaller than the smallest atom. These electrons
appear to be the building stones of the universe. No indication of any
smaller units has been discovered, although we need not assume that in
the electron science has delivered, what has been called, its
"ultim-atom." The Greeks called the elemental particles of matter
"atoms" because they esteemed them "indivisible," but now in the light
of the X-ray we can witness the disintegration of the atom into
electrons. All the chemical and physical properties of matter, except
perhaps weight, seem to depend upon the number and movement of the
negative and positive electrons and by their rearrangement one element
may be transformed into another.
So the electric furnace, where the highest attainable temperature is
combined with the divisive and directive force of the current, is a
magical machine for accomplishment of the metamorphoses desired by the
creative chemist. A hundred years ago Davy, by dipping the poles of his
battery into melted soda lye, saw forming on one of them a shining
globule like quicksilver. It was the metal sodium, never before seen by
man. Nowadays this process of electrolysis (electric loosening) is
carried out daily by the ton at Niagara.
The reverse process, electro-synthesis (electric combining), is equally
simple and even more important. By passing a strong electric current
through a mixture of lime and coke the metal calcium disengages itself
from the oxygen of the lime and attaches itself to the carbon. Or, to
put it briefly,
CaO + 3C --> CaC_{2} + CO
lime coke calcium carbon
carbide monoxide
Public-domain text, read in full here on John Shaqi.
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