Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The other and more difficult metamorphosis of carbon, the transformation
of charcoal into diamond, was successfully accomplished by Moissan in
1894. Henri Moissan was a toxicologist, that is to say, a Professor of
Poisoning, in the Paris School of Pharmacy, who took to experimenting
with the electric furnace in his leisure hours and did more to
demonstrate its possibilities than any other man. With it he isolated
fluorine, most active of the elements, and he prepared for the first
time in their purity many of the rare metals that have since found
industrial employment. He also made the carbides of the various metals,
including the now common calcium carbide. Among the problems that he
undertook and solved was the manufacture of artificial diamonds. He
first made pure charcoal by burning sugar. This was packed with iron in
the hollow of a block of lime into which extended from opposite sides
the carbon rods connected to the dynamo. When the iron had melted and
dissolved all the carbon it could, Moissan dumped it into water or
better into melted lead or into a hole in a copper block, for this
cooled it most rapidly. After a crust was formed it was left to solidify
slowly. The sudden cooling of the iron on the outside subjected the
carbon, which was held in solution, to intense pressure and when the bit
of iron was dissolved in acid some of the carbon was found to be
crystallized as diamond, although most of it was graphite. To be sure,
the diamonds were hardly big enough to be seen with the naked eye, but
since Moissan's aim was to make diamonds, not big diamonds, he ceased
his efforts at this point.
To produce large diamonds the carbon would have to be liquefied in
considerable quantity and kept in that state while it slowly
crystallized. But that could only be accomplished at a temperature and
pressure and duration unattainable as yet. Under ordinary atmospheric
pressure carbon passes over from the solid to the gaseous phase without
passing through the liquid, just as snow on a cold, clear day will
evaporate without melting.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account