Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
But although Mendeleef's law told "the truth," it gradually became
evident that it did not tell "the whole truth and nothing but the
truth," as the lawyers put it. As usually happens in the history of
science the hypothesis was found not to explain things so simply and
completely as was at first assumed. The anomalies in the arrangement did
not disappear on closer study, but stuck out more conspicuously. Though
Mendeleef had pointed out three missing links, he had failed to make
provision for a whole group of elements since discovered, the inert
gases of the helium-argon group. As we now know, the scheme was built
upon the false assumptions that the elements are immutable and that
their atomic weights are invariable.
The elements that the chemists had most difficulty in sorting out and
identifying were the heavy metals found in the "rare earths." There were
about twenty of them so mixed up together and so much alike as to baffle
all ordinary means of separating them. For a hundred years chemists
worked over them and quarreled over them before they discovered that
they had a commercial value. It was a problem as remote from
practicality as any that could be conceived. The man in the street did
not see why chemists should care whether there were two didymiums any
more than why theologians should care whether there were two Isaiahs.
But all of a sudden, in 1885, the chemical puzzle became a business
proposition. The rare earths became household utensils and it made a big
difference with our monthly gas bills whether the ceria and the thoria
in the burner mantles were absolutely pure or contained traces of some
of the other elements that were so difficult to separate.
This sudden change of venue from pure to applied science came about
through a Viennese chemist, Dr. Carl Auer, later and in consequence
known as Baron Auer von Welsbach. He was trying to sort out the rare
earths by means of the spectroscopic method, which consists ordinarily
in dipping a platinum wire into a solution of the unknown substance and
holding it in a colorless gas flame. As it burns off, each element gives
a characteristic color to the flame, which is seen as a series of lines
when looked at through the spectroscope. But the flash of the flame from
the platinum wire was too brief to be studied, so Dr. Auer hit upon the
plan of soaking a thread in the liquid and putting this in the gas jet.
The cotton of course burned off at once, but the earths held together
and when heated gave off a brilliant white light, very much like the
calcium or limelight which is produced by heating a stick of quicklime
in the oxy-hydrogen flame. But these rare earths do not require any such
intense heat as that, for they will glow in an ordinary gas jet.
Public-domain text, read in full here on John Shaqi.
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