Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
In the chapter on explosives I explained how cellulose treated with
nitric acid in the presence of sulfuric acid was nitrated. The cellulose
molecule having three hydroxyl (--OH) groups, can take up one, two or
three nitrate groups (--ONO_{2}). The higher nitrates are known as
guncotton and form the basis of modern dynamite and smokeless powder.
The lower nitrates, known as pyroxylin, are less explosive, although
still very inflammable. All these nitrates are, like the original
cellulose, insoluble in water, but unlike the original cellulose,
soluble in a mixture of ether and alcohol. The solution is called
collodion and is now in common use to spread a new skin over a wound.
The great war might be traced back to Nobel's cut finger. Alfred Nobel
was a Swedish chemist--and a pacifist. One day while working in the
laboratory he cut his finger, as chemists are apt to do, and, again as
chemists are apt to do, he dissolved some guncotton in ether-alcohol and
swabbed it on the wound. At this point, however, his conduct diverges
from the ordinary, for instead of standing idle, impatiently waving his
hand in the air to dry the film as most people, including chemists, are
apt to do, he put his mind on it and it occurred to him that this sticky
stuff, slowly hardening to an elastic mass, might be just the thing he
was hunting as an absorbent and solidifier of nitroglycerin. So instead
of throwing away the extra collodion that he had made he mixed it with
nitroglycerin and found that it set to a jelly. The "blasting gelatin"
thus discovered proved to be so insensitive to shock that it could be
safely transported or fired from a cannon. This was the first of the
high explosives that have been the chief factor in modern warfare.
But on the whole, collodion has healed more wounds than it has caused
besides being of infinite service to mankind otherwise. It has made
modern photography possible, for the film we use in the camera and
moving picture projector consists of a gelatin coating on a pyroxylin
backing. If collodion is forced through fine glass tubes instead of
through a slit, it comes out a thread instead of a film. If the
collodion jet is run into a vat of cold water the ether and alcohol
dissolve; if it is run into a chamber of warm air they evaporate. The
thread of nitrated cellulose may be rendered less inflammable by taking
out the nitrate groups by treatment with ammonium or calcium sulfide.
This restores the original cellulose, but now it is an endless thread of
any desired thickness, whereas the native fiber was in size and length
adapted to the needs of the cottonseed instead of the needs of man. The
old motto, "If you want a thing done the way you want it you must do it
yourself," explains why the chemist has been called in to supplement the
work of nature in catering to human wants.
Public-domain text, read in full here on John Shaqi.
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