Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Mark Twain said that he could understand something about how astronomers
could measure the distance of the planets, calculate their weights and
so forth, but he never could see how they could find out their names
even with the largest telescopes. This is a joke in astronomy but it
is not in chemistry. For when the chemist finds out the structure
of a compound he gives it a name which means that. The stuff came
to be called "caoutchouc," because that was the way the Spaniards
of Columbus's time caught the Indian word "cahuchu." When
Dr. Priestley called it "India rubber" he told merely where it
came from and what it was good for. But when Harries named it
"1-5-dimethyl-cyclo-octadien-1-5" any chemist could draw a picture of it
and give a guess as to how it could be made. Even a person without any
knowledge of chemistry can get the main point of it by merely looking at
this diagram:
C C C---C
|| || || |
C--C C C--C C
| | --> | |
C C--C C C--C
|| || | ||
C C C---C
[Illustration: isoprene _turns into_ caoutchouc]
I have dropped the 16 H's or hydrogen atoms of the formula for
simplicity's sake. They simply hook on wherever they can. You will see
that the isoprene consists of a chain of four carbon atoms (represented
by the C's) with an extra carbon on the side. In the transformation of
this colorless liquid into soft rubber two of the double linkages break
and so permit the two chains of 4 C's to unite to form one ring of
eight. If you have ever played ring-around-a-rosy you will get the idea.
In Chapter IV I explained that the anilin dyes are built up upon the
benzene ring of six carbon atoms. The rubber ring consists of eight at
least and probably more. Any substance containing that peculiar carbon
chain with two double links C=C-C=C can double up--polymerize, the
chemist calls it--into a rubber-like substance. So we may have many
kinds of rubber, some of which may prove to be more useful than that
which happens to be found in nature.
With the structural formula of Harries as a clue chemists all over the
world plunged into the problem with renewed hope. The famous Bayer dye
works at Elberfeld took it up and there in August, 1909, Dr. Fritz
Hofmann worked out a process for the converting of pure isoprene into
rubber by heat. Then in 1910 Harries happened upon the same sodium
reaction as Matthews, but when he came to get it patented he found that
the Englishman had beaten him to the patent office by a few weeks.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account