If a second prism be cut complementarily to the first, that is, so that
the refracting edge is parallel to the third axis of the ellipsoid (the
direction of transmission through the first prism) and the bisecting
plane again parallel to one of the three axial planes of the ellipsoid,
such a prism will also yield two refracted images corresponding to two
indices; one of them, that particular image the vibrations of which are
parallel to the refracting edge, will correspond to that one of the
three principal indices which was not given by the first prism, while
the other one will afford a duplicate determination of one of the two
indices afforded by the first prism. Hence, a couple of such axially
orientated prisms of a rhombic, monoclinic, or triclinic crystal will
enable us to determine all three refractive indices, and one of them in
duplicate, which latter fact will enable us to check the accuracy of our
work.
If the 60°-prism be cut from a crystal of the uniaxial group, that is,
from a hexagonal, tetragonal, or trigonal crystal—quartz or calcite
being admirable examples of the latter and particularly suitable for
demonstration purposes—it will generally afford two spectra in the same
manner as a crystal of the three birefringent systems of lower symmetry.
But there is one special mode of cutting which results in the prism
exhibiting only a single spectrum, namely, when the hexagonal,
tetragonal, or trigonal axis of symmetry, which is also the unique
“optic axis” of the crystal along which there is no double refraction,
is arranged to be perpendicular to the bisecting plane of the 60°-prism.
For then the light is transmitted along this unique axial direction when
the prism is arranged for the minimum deviation of the refracted rays
out of their original path, and as it may vibrate in any direction
perpendicular thereto with equal velocity there is no separation into
two rays, that is, no double refraction, and thus only a single spectrum
is afforded by such a prism in white light, or a single image of the
slit in monochromatic light, and this latter will at once yield the
refractive index which is generally indicated conventionally by the
letter ω, corresponding to light vibrations perpendicular to the axis.
Spectroscopists take advantage of this interesting fact, when they
employ a train of quartz prisms so cut in order to explore the violet
and ultra-violet region of the spectrum; for quartz transmits many of
the ultra-violet rays which glass absorbs. Each prism gives only a
single image like glass, whereas if it were otherwise cut it would give
two spectra, which would so complicate matters as to render quartz
useless for the purpose.
Public-domain text, read in full here on John Shaqi.
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