It is obvious, therefore, that the colours of these thicker plates of
quartz are due to the phenomenon of “optical activity.” The original
plane of polarisation of the light received from the polarising Nicol is
rotated by the quartz plate, and to an extent which is directly
proportional to the thickness. When white light is used a particular
colour is extinguished for each position of the analyser, and the
complementary colour therefore predominates in the tint actually
exhibited. Now the most intensely luminous part of the spectrum is about
wave-length 0.000550 millimetre in the yellow, and in the case of a
plate of quartz 7.5 millimetres thick this colour is extinguished when
the Nicols are crossed, while a plate of half this thickness, 3.75 mm.,
actually exhibits the colour under crossed Nicols and extinguishes it
under parallel Nicols. For the angle of rotation of the plane of
polarisation for light of this wave-length is 90° for a plate 3.75 mm.
thick, so that the analyser has to be turned through a right angle from
the crossed position, that is, placed parallel to the polariser, in
order to extinguish this colour. A plate of double the thickness, 7.5
mm., will require the analyser to be rotated through 180°, the angle of
rotation for this thickness of plate, in order to extinguish this yellow
ray. But 180° rotation simply brings the Nicol again to the crossed
position, so that no rotation is really necessary at all.
Now the complementary colour to the yellow of wave-length 0.000550 mm.
is the transition violet tint, the well-known “tint of passage” between
the brilliant red end of the first order spectrum of Newton and the deep
blue of the beginning of the second order. Hence, this violet tint is
afforded by a plate of 7.5 mm. thickness when the Nicols are crossed,
and by a plate of 3.75 mm. thickness when they are parallel. When,
therefore, these plates are examined respectively under crossed and
parallel Nicols, and the analysing Nicol is turned ever so little, the
tint changes remarkably rapidly into brilliant red or blue, according to
the direction of the rotation of the Nicol and the nature, whether right
or left-handed, of the quartz. Moreover, when two complementary plates
of each thickness are thus examined, one of each pair being cut from a
right-handed crystal and the other from a left-handed one, the colour
will be red in one case and blue in the other for the same direction of
rotation of the analyser.
Public-domain text, read in full here on John Shaqi.
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