This colour is due to the same fact which produced colour in the central
part of the interference figure, namely, the optical activity of quartz,
the fact that the plane of vibration of a beam of plane polarised light
transmitted along the axis of quartz is rotated to the right hand or to
the left. The amount of this rotation is precisely equal, although
opposite in direction, for the two varieties of quartz, but the rotation
varies very considerably for different rays of the spectrum. It also
varies directly proportionally to the thickness of the plate. A plate
one millimetre thick cut perpendicularly to the axis rotates the plane
of polarisation for red hydrogen light (C of the spectrum) to the extent
of 17° 19′, for yellow D sodium light 21° 42′, and for greenish-blue F
hydrogen light 32° 46′. The rotation is a maximum for plates
perpendicular to the axis, and the effect is inappreciable in directions
at right angles thereto. It is clearly due to the oppositely spiral
winding of the regular-point-system of the crystal structure, round the
direction of the optic axis, the trigonal axis of symmetry of the
crystal, a structure which we have proved to be characteristic of quartz
by the beautiful experiments with the helical piles of mica plates,
absolutely reproducing the polarisation effects with quartz, as
described in the last chapter.
The opposite optical rotation of the two varieties of quartz can be well
shown by constructing a “biquartz.” Two plates of equal thickness,
preferably either 7.5 mm. or 3.75 mm., are cut, one from a right-handed
and the other from a left-handed crystal, each exactly perpendicular to
the optic axis. The two edge-surfaces to be subsequently joined together
are also cut, ground and polished as true planes perpendicular to the
plate surfaces, and the two plates are then cemented together with
Canada balsam by these two prepared edge-surfaces, taking care that the
broad plate-surfaces of the two halves are absolutely continuous as if
the whole were a single parallel-surfaced plate of quartz. Such a
composite plate or “biquartz,” is one of the most useful aids to the
study of optical activity, being much used for enhancing the
sensitiveness of the determination of the angle of rotation.
Public-domain text, read in full here on John Shaqi.
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