An interesting crystal of amethyst very similar to the third of those
just described, the one illustrated in Fig. 95, was described by Prof.
Judd in the year 1892 to the Mineralogical Society.[18] The plan of the
crystal is given in Fig. 96. The wedges marked _x_, _y_, _z_, are of a
pale yellow colour, as are also the three strips, sections of plates,
proceeding from the wedges and meeting at the centre _o_. The wedge _y_
exhibits left-handed polarisation, and the wedge _z_ right-handed. The
large wedge _x_ is composite, the part marked _x__{r} being right-handed
and that marked _x__{l} left-handed. The surface of junction of the two
parts is not perpendicular to the plate, so where the two varieties
overlap, the part marked _x__{rl}, a ribbon band is shown in parallel
light and Airy’s spirals in convergent polarised light. The yellow parts
of the crystal exhibit ordinary rotatory polarisation colours, even
tints; but in the remaining sectors of the crystal, the lines of
division of which are indicated by the radial lines A, B, C, no trace of
circular polarisation is displayed, and the central part, where the
lamellæ are very well developed, gives the ordinary calcite-like
uniaxial interference figure. The more marginal portions, however, show
complicated interference figures, somewhat resembling those of biaxial
crystals, owing to irregular distribution of the two varieties of
quartz, and probable displacement of the optic axis by distortion.
An ingenious theory of the formation of the lamellæ is put forward by
Prof. Judd in the same memoir. He had already shown that quartz is
endowed with planes of gliding, parallel to the rhombohedral faces, and
suggests that the lamellation is the result of the effect of high
pressure and possibly high temperature on the quartz crystal after its
formation. The lamellæ appear to be frequently parallel to the
rhombohedral terminal faces of the crystal, as if they were indeed glide
plane effects. It is quite conceivable that the gliding of layers of
molecules, which when permanent usually involves rotation and inversion
of the molecules, might result in alternately right and left structural
arrangements, and there is considerable evidence that the development of
the purple tint occurred subsequently to the growth of the crystal. It
is probably due to change in the state of oxidation of the trace of
manganese present as a minute impurity in the quartz crystal, and which
is concentrated between the lamellæ, just as the yellow tint is due to a
slight trace of iron (ferric) oxide. The theory is an interesting one,
and throws considerable light on the possible nature of intimate
lamellar twinning.
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