Another substance of like character, para-azoxy-anisol, was subsequently
found to behave similarly, and forms an excellent substance to use for
demonstration purposes. A reproduction of a photograph, kindly sent to
the author by Prof. Lehmann, of a slide of this substance is given in
Fig. 104, Plate XXII. It shows a characteristic field of such drops,
exhibiting white parts and yellow sectorial parts which photograph dark,
of para-azoxy-anisol mixed with a little para-azoxy-phenetol, oil and
resin (colophony), as seen under the polarising microscope with crossed
Nicols.
The next and possibly most interesting step in this remarkable series of
discoveries was made by Lehmann himself in the year 1894. He alighted on
the fact that ammonium oleate, crystallised from solution in alcohol,
affords a splendid example of flowing crystals, which are sufficiently
large to enable their habits to be studied in detail. The individuals
are almost invisible in ordinary light, owing to the refractive index of
the crystals and of the mother liquor being approximately the same. But
in polarised light, using crossed Nicols, they are clearly revealed as
steep double pyramids with more or less rounded edges. Their section is
nearly circular in consequence, and they exhibit optical properties of a
uniaxial character, the optic axis being that of the double cone or
bipyramid. A characteristic individual is shown at _e_ in Fig. 105. When
two of these flowing crystals approach each other, as at _a_ in Fig.
105, they coalesce to form a larger single individual, as is indicated
in stages at _b_, _c_, and _d_ in the illustration.
[Illustration:
FIG. 105.—Liquid Crystals of Ammonium Oleate.
]
When the cover-glass, under which they are growing on a microscope 3 by
1 inch slip, is moved to and fro so as to distort these remarkable
bodies, which we may well hesitate to call crystals, the singular effect
is produced of causing them all to become similarly orientated, for the
extinction directions follow the direction of the pressure. They at once
seek to regain their original form, however, on cessation of the
disturbance. A slide of the bipyramids under pressure is shown in Fig.
106. In the black extinguished portions of the field the flowing
crystals are flattened, according to Lehmann, and arranged so that the
optic axis is in all cases perpendicular to the tabular crystals and the
glass plates and parallel to the axis of the microscope. The black parts
are separated by oily strips, as shown in another slide under
considerable pressure, represented in Fig. 107, which are composed of
the tabular crystals standing on end, with their optic axes parallel to
the plates. These strips polarise the more brightly the more truly the
crystals stand perpendicularly to the plates. The two conditions are
shown diagrammatically at _a_ and _b_ in Fig. 108.
[Illustration:
FIG. 106.—Liquid Crystals of Ammonium Oleate under slight pressure.
]
[Illustration:
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