The individuals are described by Lehmann, who further studied the nature
of the substance, as almost perfectly rectilinear prisms with nearly
sharply defined basal plane end faces. A singular fact about this
substance is, that when two individuals approach each other they arrange
themselves parallel with a jerk, and then flow into each other,
producing a single larger liquid crystal, and often with such rapidity
that the eye can scarcely follow the movements. These coalescences
appear to be occurring all over the field at once, with the production
of larger and larger crystals. Indeed, Lehmann likens it to a struggle
between the innumerable individuals, in which the smaller ones are being
continually eaten up by the larger.
Vorländer also prepared the ethyl ester of para-azoxy-cinnamic acid, and
Lehmann found it to be similarly interesting. The substance separates
from a solution in monobromonaphthalene in uniaxial prisms or
hemimorphic pyramids, the edges and solid angles of which are more or
less rounded, and which appear colourless in the direction of the axis
and yellow in all other directions. When pressed between the cover-glass
and the micro-slip on which the crystallisation is proceeding,
extinction of the light occurs throughout the whole mass when polarised
light is being employed and the Nicols are crossed. For throughout the
entire substance the particles—whether they are the molecules themselves
as Lehmann asserts or aggregations of them in the form of
ultramicroscopic crystals—arrange themselves with their optic axes (the
crystals being uniaxial) perpendicular to the cover-glass and
micro-slip, as in the case of ammonium oleate. Lehmann’s theory is that
the molecules themselves are tabular perpendicular to the axis, as in
the case just referred to, and that they are thus readily coerced by the
pressure of the flat cover-glass to take up positions parallel to it.
Two further reproductions of photographs, taken in polarised light, of a
somewhat remarkable character, which have been placed at the author’s
disposal by the courtesy of Prof. Lehmann, are given in Figs. 113 and
114, Plate XXIII. Fig. 113 represents numerous doubly refractive and
dichroic strips marking the boundaries of elongated individual crystals
of the substance dibenzal benzidine, and affords a graphic idea of the
real character of the double refraction displayed by liquid crystals.
[Illustration:
_PLATE XXIII._
FIG. 113.—Elongated Liquid Crystals of Dibenzal Benzidine, showing
Double Refraction and Dichroism.
]
[Illustration:
FIG. 114.—Spherical Liquid Crystals of Para-azoxy-anisol, showing
Interference Colours under Crossed Nicols as the Effect of
Compression.
]
Fig. 114 represents the effect of compression on para-azoxy-anisol, and
demonstrates very clearly the distribution of the interference colours
due to double refraction.
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