Schönflies’ simple definition of the nature of the structure is that
every molecule is surrounded by the rest collectively in like manner,
when likeness may be either identity or mirror-image resemblance. Von
Fedorow finds the extra 165 types to be comprised in “double systems”
consisting of two “analogous systems” which are the mirror images of
each other. Barlow proceeds to find in how many ways the two
mirror-image forms can be combined together, there being in general
three distinct modes of duplication, including the insertion of one
inside the other. He also shows that all homologous points in a
structure of the type of one of these additional 165 point-systems
together form one of the 65 Sohnckian point-systems, the structure being
capable of the same rotations or translations, technically known as
“coincidence movements” (movements which bring the structure to exhibit
the same appearance as at first), as those which are characteristic of
that point-system.
This fascinating subject of mirror-image symmetry, and the optical
activity connected with it, will be reverted to and the latter explained
in Chapter XI.
We have thus seen how satisfactorily the geometrical theory of the
homogeneous partitioning of space has been worked out, and how admirably
it agrees with our preliminary supposition that a crystal is a
homogeneous structure. The fact that the 230 homogeneous point-systems
all fall into and distribute themselves among the thirty-two classes of
crystals, the symmetry of which has also now been fully established,
affords undeniable proof that as regards this branch of the subject
something like finality and clearness of vision has now been arrived at.
CHAPTER X
LAW OF VARIATION OF ANGLES IN ISOMORPHOUS SERIES. RELATIVE DIMENSIONS OF
UNIT CELLS. FIXITY OF ATOMS IN CRYSTAL.
We are now in a position to approach the conclusion of the long
controversy as to the constancy or otherwise of crystal angles in
the cases of greatest similarity, those of isomorphous substances,
and to appreciate how the conflicting views of Haüy and Mitscherlich
and their schools of thought have at length been reconciled. As the
result of a comprehensive study, on the part of the author, of the
sulphates and selenates of the rhombic series R_{2}S/SeO_{4}, and of
the double sulphates and selenates of the monoclinic series
R_{2}M(S/SeO_{4})_{2}.6H_{2}O, in which R represents the alkali
metals, potassium, rubidium and cæsium, and in which M may be
magnesium, zinc, iron, nickel, cobalt, manganese, copper or cadmium,
four facts of prime significance have been definitely established.
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