Thus it is clear that in the cases of isomorphous substances, which were
the only possible exceptions to the generalisation that _to every
chemically distinct solid substance of other than perfect cubic symmetry
there appertains a specific crystalline form, endowed with its own
particular angles and morphological crystal elements, which are
absolutely constant for the same temperature_, the law does really hold,
and isomorphous substances are no exceptions. The law of progression of
the crystal properties according to the atomic weight of the
interchangeable elements affords indeed at the same time both an
amplification of the generalisation and a precise explanation of its
mode of operation in these cases.
The discovery of the local effect produced by the two kinds, positive
and negative, of chemical replacement, has a profound bearing on crystal
structure. For it is thereby rendered certain that the atoms are fixed
in the crystal edifice, and therefore in the molecule in the solid
state. It becomes obvious that the atoms—in their stereometric positions
in the molecule, being thus fixed in the solid crystal when the
molecules set themselves rigidly in the regular organisation of the
space-lattice—form the points of the regular point-system of the crystal
structure, which determines to which of the thirty-two classes of
symmetry the crystal shall belong. Any movement of the atoms in the
crystal, other than that which accompanies change of temperature, and
possibly change of pressure, is thus improbable; and this experimental
proof of their fixity, afforded by the fact that definitely orientated
changes accompany the replacement of particular atoms, also doubtless
indicates that the latter are located in the particular directions along
which the changes of exterior angle and of internal structural
dimensions are observed to occur. Stereo-chemistry, which has made such
enormous advances during the last few years, thus becomes of even
greater importance than Wislicenus and its other originators ever dreamt
of.
Within the atoms in the crystal the constituent electronic corpuscles
may be and probably are in rapid movement, and such physical effects as
have hitherto been ascribed to movement of the atoms within the crystal
are doubtless due to movement of the electronic corpuscles within them,
the sphere of influence of the atom itself being fixed in space in the
solid crystal, and being doubtless defined by the area within which the
corpuscular movements occur.
[Illustration:
FIG. 60.—Diagram illustrating Progressive Change of Crystal Angles in
Isomorphous Series.
]
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