Three illustrations of the law of change of the crystal properties with
variation of the atomic weight of the determinative elements of an
isomorphous series may be given, and will serve to render the practical
meaning of the generalisation clearer. The first is a diagrammatic
representation, in Fig. 60 (in a very exaggerated manner as the real
change would be inappreciable on the scale drawn), of the change of
angle on replacing the potassium in potassium sulphate, K_{2}SO_{4}, or
selenate, K_{2}SeO_{4}, by rubidium or cæsium. The inner crystal
outline, a vertical section, is that of the potassium salt. The vertical
lines represent the intersections of the two faces of the brachypinakoid
_b_ = {010} with a vertical plane parallel to the macropinakoid _a_ =
{100}; the horizontal lines represent the intersection of the two faces
of the basal plane _c_ = {001} with the same vertical plane; and the
oblique lines represent the intersection of the vertical plane with the
four faces of the dome form _q_ = {011}, which are inclined to both _b_
and _c_ planes. The diagram is thus designed to show the variation of
the inclination of these latter dome faces to the two rectangular axial
plane faces _b_ and _c_. The outer crystal outline represents a similar
section of a crystal of the corresponding cæsium salt, and the middle
outline that of a crystal of the rubidium salt.
The progressive alteration of the angle of the q-face will be obvious,
the direction of the change being correct, but the amount of change, as
already stated, being much exaggerated; in reality it never reaches a
degree between the two extreme (potassium and cæsium) salts. It will be
remembered that the respective atomic weights of potassium, rubidium,
and cæsium are 38·85, 84·9 and 131·9, when hydrogen equals 1, that of
rubidium being almost exactly the mean.
[Illustration:
FIG. 61.—Diagram illustrating Progressive Change of Double Retraction
in Isomorphous Series.
]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account