Hence the conception of a physical molecule is totally unnecessary and,
moreover, erroneous. The alkali sulphates and selenates exhibit
dimorphism, one member of the series, ammonium selenate, having only
hitherto been observed in the pure state in the second, monoclinic,
form, and never in the ordinary rhombic form; and the author has
conclusively proved for these salts, and also for the double salts which
they form with the sulphates and selenates of magnesium, zinc, iron,
nickel, cobalt, manganese, copper, and cadmium, that the chemical
molecule is the only kind of molecule present, and that its
representative points are, as just stated, the nodes of the Bravais
space-lattice of the crystal structure, determining both the system of
the crystal and its obedience to the law of rational indices.
The explanation of polymorphism thus proves, in the light of the results
which have now been laid before the reader, to be a remarkably simple
one. Special pains were taken in explaining those results to show that
the temperature had a great deal to do with the conditions of
equilibrium of the crystal structure, for it determines the
intermolecular distances, that is, the amount of separation of the
molecules, and thus controls their possibility of movement with respect
to one another. Now the behaviour of the chemical molecules on the
advent of crystallisation is undoubtedly largely influenced by the
stereometric arrangement of the atoms composing them, and it is possible
for the latter to be such that the molecules may take up several
different parallel or enantiomorphously related positions; or as we have
just seen, a regular alternation within the crystal structure of such
mirror-image positions may be taken up. These different arrangements,
whether parallel or enantiomorphously opposite, may be, and probably
will be, of different degrees of stability, each of these different
forms finding its maximum stability of equilibrium at some particular
temperature, which is different for the different varieties. Hence, at a
series of ascending or descending temperatures, assuming the pressure to
remain the ordinary atmospheric, these different types of homogeneous
crystal structures will be most liable to be produced, each at its own
particular temperature, for which stable equilibrium of that crystal
structure occurs.
These different assemblages are as a rule quite dissimilar, certainly in
the crystal elements, often in class and not infrequently in system.
Generally two such different crystalline forms are all that are possible
within the life-range of temperature of the substance. But occasionally
three or even as many as four such different forms are found to be
capable of existence within the temperature life-limits of the
substance.
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