The optical properties of calcium dextro-glycerate thus confirm
absolutely the monoclinic nature of the symmetry, as regards the crystal
system. And it was conclusively demonstrated by the goniometrical part
of the investigation that the exterior symmetry was not such as agreed
with holohedral monoclinic symmetry, but with that of the sphenoidal
class, in which the only one of the two elements of monoclinic symmetry
(the plane of symmetry and the digonal axis of symmetry) in operation is
the digonal axis, thus leaving the two terminations of that axis, at
opposite sides, right and left, of the possible symmetry plane,
unsymmetrical. And this is precisely the symmetry which is
characteristic of an enantiomorphous optically active substance.
Unfortunately, the corresponding lævo-salt has not yet been obtained in
measurable crystals, but there can be no doubt that whenever such are
forthcoming they will display enantiomorphism in the precisely opposite
and complementary sense, the facial forms characteristic in this
dextro-salt of the right termination of the digonal axis being absent on
that side of the systematic symmetry plane but developed on the left
side instead, and _vice versa_, and that the two enantiomorphous forms
will together make up the whole of the faces required by the full
symmetry of the monoclinic system.
A concrete instance like this, worked out practically in the laboratory,
brings home the precise nature of this interesting relationship, between
crystallographic and molecular enantiomorphism on the one hand and
optical activity on the other hand, in a particularly clear and forcible
manner. It is hoped that this brief account of it will also consequently
have been of assistance to the reader, in more clearly appreciating the
main points of this chapter.
CHAPTER XII
EFFECT OF THE SYMMETRY OF CRYSTALS ON THE PASSAGE OF LIGHT THROUGH THEM.
QUARTZ, CALCITE, AND GYPSUM AS EXAMPLES.
The action of transparent crystals on the rays of light which they
transmit is a subject not only of the deepest interest, but also of the
utmost importance. For it is immediately possible to detect a cubic
crystal, and to discriminate between two groups, optically uniaxial and
biaxial respectively, of the other six systems of symmetry, three
systems going to each group, by this means alone. For a cubic crystal is
singly refractive in all directions. A 60°-prism, for instance, cut from
a cube of rock-salt, for the purpose of obtaining the refractive index
of the mineral by the ordinary method of producing a spectrum and
arranging it for minimum deviation of the refracted rays, affords but a
single spectrum, or a single sharp image of the spectrometer slit when
the latter is fed by pure monochromatic light instead of ordinary white
light. This is true however the prism may have been cut, as regards its
orientation with respect to the natural crystal faces.
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