Eclectic Magazine of Foreign Literature, Science, and Art, April 1885Various
General
Eclectic Magazine of Foreign Literature, Science, and Art, April 1885
Various
American literature -- Periodicals; Literature -- Periodicals
me be your bottle-washer”—that the good-hearted Cornishman took the
poor blacksmith’s son, then twenty-one years old, after eight years of
book-stitching, and made him his assistant, “keeping him in his place,”
nevertheless, which, for an assistant in those days, meant feeding with
the servants, except by special invitation.
This was in 1823, and next year Faraday had liquefied chlorine,
and soon did the same for a dozen more gases, among them protoxide
of nitrogen, to liquefy which, at a temperature of fifty degrees
Fahrenheit, was needed a pressure of sixty atmospheres—sixty times
the pressure of the air—i.e., nine hundred pounds on every square
inch. Why, the strongest boilers, with all their thickness of iron,
their rivets, their careful hammering of every plate to guard against
weak places, are only calculated to stand about ten atmospheres; no
wonder then that Faraday, with nothing but thick glass tubes, had
thirteen explosions, and that a fellow-experimenter was killed while
repeating one of his experiments. However, he gave out his “Law,” that
any gas may be liquefied if you put pressure enough on it. That “if”
would have left matters much where they were had not Bussy, in 1824,
argued: “Liquid is the middle state between gaseous and solid. Cold
turns liquids into solids; therefore, probably cold will turn gases
into liquids.” He proved this for sulphurous acid, by simply plunging
a bottle of it in salt and ice; and it is by combining the two, cold
and pressure, that all subsequent results have been attained. How
to produce cold, then, became the problem; and one way is by making
steam. You cannot get steam without borrowing heat from something.
Water boils at two hundred and twelve degrees Fahrenheit, and then
you may go on heating and heating till one thousand degrees more heat
have been absorbed before steam is formed. The thermometer, meanwhile,
never rises above two hundred and twelve degrees, all this extra heat
becoming what is called latent, and is probably employed in keeping
asunder the particles which when closer together form water. The
greater the expansive force, the more heat becomes latent or used up
in this way. This explains the paradox that, while the steam from a
kettle-spout scalds you, you may put your hand with impunity into the
jet discharged from a high-pressure engine. The high-pressure steam,
expanding rapidly when it gets out of confinement, uses up all its
heat (makes it all “latent”) in keeping its particles distinct. It is
the same with all other vapors: in expanding they absorb heat, and,
therefore, produce cold; and, therefore, as many substances turn into
steam at far lower temperatures than water does, this principle of
“latent heat,” invented by Black, and, after long rejection, accepted
by chemists, has been very helpful in the liquefying of gases by
producing cold.
Public-domain text, read in full here on John Shaqi.
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