Eclectic Magazine of Foreign Literature, Science, and Art, April 1885Various
General
Eclectic Magazine of Foreign Literature, Science, and Art, April 1885
Various
American literature -- Periodicals; Literature -- Periodicals
Amid these and such-like curious experiments, we must not forget the
“Law” that the state of a substance depends on its temperature—solid
when it is frozen hard enough, liquid under sufficient pressure,
gaseous when free from pressure and at a sufficiently high temperature.
But though first Faraday, and then the various inventors of
refrigerating-machines—Carré, Tellier, Natterer, Thilorier—succeeded
in liquefying so many gases, hydrogen and the two elements of the
atmosphere resisted all efforts. By plunging oxygen in the sea,
to the depth of a league, it was subjected to a pressure of four
hundred atmospheres, but there was no sign of liquefaction. Again,
Berthelot fastened a tube, strong and very narrow, and full of air,
to a bulb filled with mercury. The mercury was heated until its
expansion subjected the air to a pressure of seven hundred and eighty
atmospheres—all that the glass could stand—but the air remained
unchanged. Cailletet managed to get one thousand pressures by pumping
mercury down a long, flexible steel tube upon a very strong vessel,
full of air; but nothing came of it, except the bursting of the vessel,
nor was there any more satisfactory result in the case of hydrogen.
One result, at any rate, was established—that there is no law of
compression like that named after Boyle or Mariotte, but that every gas
behaves in a way of its own, without reference to any of the others,
each having its own “critical point” of temperature, at which, under
a certain pressure, it is neither liquid nor gaseous, but on the
border-land between the two, and will remain in this condition so long
as the temperature remains the same. Hence, air being just in this
state of gaseo-liquid, the first step towards liquefying it must be
to lower its temperature, and so get rid of its vapor by increasing
its density. The plan adopted, both by Cailletet in Paris, and by
Raoul Pictet (heir of a great scientific name) in Geneva, was to lower
the temperature by letting off high-pressure steam. This had been so
successful in the case of carbonic acid gas as to turn the vapor into
snow; and in 1877 Cailletet pumped oxygen into a glass tube, until the
pressure was equal to three hundred atmospheres. He then cooled it to
four degrees Fahrenheit below zero, and, opening a valve, let out a jet
of gaseous vapor, which, while expanding, caused intense cold, lowering
the temperature some three hundred degrees, and turning the jet of
vapor into fog. Here, then, was a partial liquefaction, and the same
was effected in the case of nitrogen. Pictet did much the same thing.
Having set up at Geneva a great ice-works (his refrigerating agency
being sulphurous acid in a boiling state), he had all the necessary
apparatus, and was able to subject oxygen to a pressure of three
hundred and twenty atmospheres, and by means of carbonic acid boiling
in vacuo, to cool the vessel containing it down to more than two
hundred degrees Fahrenheit below zero.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account