As far back as 1785 it was noticed that oxygen became changed in
some way when an electric spark was passed through it, and that it
acquired a peculiar odour. No particular attention was paid to the
matter however until about 1840, when Schönbein, a famous German
chemist, and the discoverer of gun-cotton and collodion, became
interested in it. He gave this strange smelling substance the name of
“ozone,” and he published the results of his experiments with it in
a treatise entitled, “On the Generation of Ozone.” Schönbein showed
that ozone could be produced by various methods, chemical as well as
electrical. For instance, if a piece of phosphorus is suspended in
a jar of air containing also a little water, in such a manner that
it is partly in the water and partly out of it, the air acquires
the characteristic smell of ozone, and it is found to have gained
increased chemical energy, so that it is a more powerful oxidizing
agent. For a long time the exact chemical nature of ozone could not be
determined, mainly because it was impossible to obtain the substance
in quantities sufficiently large for extensive experimental research,
but also on account of its extremely energetic properties, which made
it very troublesome to examine. These difficulties were so great that
investigators were in doubt as to whether ozone was an element or a
compound of two or more elements; but finally it was proved that it was
simply oxygen in a condensed or concentrated state.
Apparently ozone is formed by the contraction of oxygen, so that from
three volumes of oxygen two volumes of ozone are produced. In other
words, ozone has one and a half times the density of oxygen. Ozone has
far greater oxidizing power than oxygen itself; in fact it is probably
the most powerful of all oxidizing agents, and herein lies its great
value. It acts as nature’s disinfectant or sterilizer, and plays a very
important part in keeping the air pure, by destroying injurious organic
matter. Bacteria apparently have a most decided objection to dying; at
any rate they take an extraordinary amount of killing. Ozone is more
than a match for them however, and under its influence they have a
short life and probably not a merry one.
Ozone exists naturally in the atmosphere in the open country, and more
especially at the seaside. It is produced by lightning discharges, by
silent electrical discharges in the atmosphere, by the evaporation of
water, particularly salt water, by the action of sunlight, and also by
the action of certain vegetable products upon the air. The quantity
of ozone in the air is always small, and even pure country or sea air
contains only one volume of ozone in about 700,000 volumes of air. No
ozone can be detected in the air of large towns, or over unhealthy
swamps or marshes. The exhilarating effects of country and sea air,
and the depressing effects of town air, are due to a very large extent
to the presence or absence of ozone.
Public-domain text, read in full here on John Shaqi.
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