A current of electricity is believed to be nothing more or less
than a stream of electrons, set in motion by the application of
an electro-motive force. We have seen that some substances are
good conductors of electricity, while others are bad conductors or
non-conductors. In order to produce an electric current, that is a
current of electrons, it is evidently necessary that the electrons
should be free to move. In good conductors, which are mostly metals,
it is believed that the electrons are able to move from atom to atom
without much hindrance, while in a non-conductor their movements are
hampered to such an extent that inter-atomic exchange of electrons is
almost impossible. Speaking on this point, Professor Fleming says:
“There may be (in a good conductor) a constant decomposition and
recomposition of atoms taking place, and any given electron so to speak
flits about, now forming part of one atom and now of another, and anon
enjoying a free existence. It resembles a person visiting from house
to house, forming a unit in different households, and, in between,
being a solitary person in the street. In non-conductors, on the other
hand, the electrons are much restricted in their movements, and can be
displaced a little way but are pulled back again when released.”
Let us try to see now how an electric current is set up in a simple
voltaic cell, consisting of a zinc plate and a copper plate immersed in
dilute acid. First we must understand the meaning of the word _ion_.
If we place a small quantity of salt in a vessel containing water, the
salt dissolves, and the water becomes salt, not only at the bottom
where the salt was placed, but throughout the whole vessel. This means
that the particles of salt must be able to move through the water.
Salt is a chemical compound of sodium and chlorine, and its molecules
consist of atoms of both these substances. It is supposed that each
salt molecule breaks up into two parts, one part being a sodium atom,
and the other a chlorine atom; and further, that the sodium atom loses
an electron, while the chlorine atom gains one. These atoms have the
power of travelling about through the solution, and they are called
_ions_, which means “wanderers.” An ordinary atom is unable to wander
about in this way, but it gains travelling power as soon as it is
converted into an ion, by losing electrons if it be an atom of a metal,
and by gaining electrons if it be an atom of a non-metal.
Public-domain text, read in full here on John Shaqi.
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