Elements of Agricultural ChemistryAnderson, Thomas
Science
Elements of Agricultural Chemistry
Anderson, Thomas
Agricultural chemistry
The true marls, that is those in which carbonate of lime abounds, are
greatly preferable to clay marls, the latter, indeed, operate chiefly
mechanically, by altering the texture of the soil--the lime they contain
being frequently too small to exercise much appreciable effect.
Shell and coral sands consist chiefly of fragments of shells and coral
disintegrated by the action of the waves, and mixed with more or less
siliceous sand, and containing small quantities of phosphate of lime.
They occur to a considerable extent both on our own coasts and those of
France, and have been used with good effect on some descriptions of
soil.
The general composition of limestones has been already adverted to,
when treating of the origin of soils, and a distinction drawn between
the common limestones and dolomite or magnesium limestone. Few
limestones can be considered as even approaching to purity, and they
almost all contain a small quantity of carbonate of magnesia as well as
earthy matters, and occasionally a little phosphate of lime. In good
specimens the quantities of these substances are generally small, and
they usually contain about half their weight of lime. When limestone is
burnt in the kiln, the change which ensues consists in the expulsion of
the carbonic acid, and the consequent conversion of the lime into the
uncombined or quick state. If water be thrown upon it when in this
condition, it becomes hot, swells up, and falls to a fine soft powder,
and has then entered into combination with water. If it be exposed to
the air, the same action takes place, although, of course, more slowly;
and if it be left for a sufficient time, it at length absorbs carbonic
acid, and reverts to its original form of carbonate of lime, although
now in a state of very fine division.
While lime may be applied in the state of carbonate, either as chalk,
marl, or pounded limestone, and with a certain amount of advantage, much
greater effects are obtained from the use of lime itself in the quick or
slaked state. These advantages are dependent partly on the mechanical
effect of the burning and slaking, which enable us to reduce the lime to
a much more minute state of division, and consequently to incorporate it
more uniformly and thoroughly with the soil, and partly on the more
powerful chemical action which it exists when in the quick or caustic
state. Other minor advantages are also secured, such as the production
of a certain quantity of sulphate of lime, produced by the oxidation of
the sulphur of the coal used in burning, etc., which, though
comparatively trifling, may, under particular circumstances and in some
soils, be of considerable importance.
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