Elements of Chemistry,: In a New Systematic Order, Containing all the Modern DiscoveriesLavoisier, Antoine Laurent
Science
Elements of Chemistry,: In a New Systematic Order, Containing all the Modern Discoveries
Lavoisier, Antoine Laurent
Chemistry -- Early works to 1800
The muriatic acid has only a moderate adherence to the salifiable bases,
and can readily be driven from its combination with these by sulphuric
acid. Other acids, as the nitric, for instance, may answer the same
purpose; but nitric acid being volatile, would mix, during
distillation, with the muriatic. About one part of sulphuric acid is
sufficient to decompose two parts of decrepitated sea-salt. This
operation is performed in a tubulated retort, having Woulfe's apparatus,
(Pl. IV. Fig. 1.), adapted to it. When all the junctures are properly
lured, the sea-salt is put into the retort through the tube, the
sulphuric acid is poured on, and the opening immediately closed with its
ground crystal stopper. As the muriatic acid can only subsist in the
gaseous form in the ordinary temperature, we could not condense it
without the presence of water. Hence the use of the water with which the
bottles in Woulfe's apparatus are half filled; the muriatic acid gas,
driven off from the sea-salt in the retort, combines with the water, and
forms what the old chemists called _smoaking spirit of salt_, or
_Glauber's spirit of sea-salt_, which we now name _muriatic acid_.
The acid obtained by the above process is still capable of combining
with a farther dose of oxygen, by being distilled from the oxyds of
manganese, lead, or mercury, and the resulting acid, which we name
_oxygenated muriatic acid_, can only, like the former, exist in the
gasseous form, and is absorbed, in a much smaller quantity by water.
When the impregnation of water with this gas is pushed beyond a certain
point, the superabundant acid precipitates to the bottom of the vessels
in a concrete form. Mr Berthollet has shown that this acid is capable
of combining with a great number of the salifiable bases; the neutral
salts which result from this union are susceptible of deflagrating with
charcoal, and many of the metallic substances; these deflagrations are
very violent and dangerous, owing to the great quantity of caloric which
the oxygen carries alongst with it into the composition of oxygenated
muriatic acid.
TABLE _of the Combinations of Nitro-muriatic Acid with the Salifiable
Bases, in the Order of Affinity, so far as is known._
_Names of the Bases._ _Names of the Neutral Salts._
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