Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Substances which abound much in Oil, being bruised and triturated
with water for some time, afford a liquor of an opaque dead-white
colour, like milk. This liquor consists of such juices as the water is
capable of dissolving, together with a portion of the oil, which being
naturally indissoluble in water, is only divided and dispersed in the
liquor, the limpidity whereof is by that means destroyed. This sort of
oily liquor, in which the oil is only divided, not dissolved, is called
an _Emulsion_. The oily particles in Emulsions spontaneously separate
from the water, when left at rest, and uniting into greater masses
rise, on account of their lightness, to the surface of the liquor,
which by that means recovers a degree of transparency.
If vegetables abounding in essential oils and resins be digested in
spirit of wine, the menstruum takes up these oily matters, as being
capable of dissolving them; and they may afterwards be easily separated
from it by the affusion of water. The water, with which spirit of wine
has a greater affinity than with oily matters, separates them by this
means from their solvent, agreeably to the common laws of affinities.
Without the help of fire, scarce any thing, besides the substances
already mentioned, can be obtained from a plant: but, by the means
of distillation, we are enabled to analyse them more completely.
In prosecuting this method of extracting from a plant the several
principles of which it consists, the following order is to be observed.
A plant being exposed to a very gentle heat, in a distilling vessel set
in the _balneum mariæ_, yields a water which retains the perfect smell
thereof. Some Chymists, and particularly the illustrious Boerhaave,
have called this liquor the _Spiritus Rector_. The nature of this
odoriferous part of plants is not yet thoroughly known; because it is
so very volatile that it is difficult to subject it to the experiments
necessary for discovering all its properties.
If, instead of distilling the plant in the _balneum mariæ_, it be
distilled over a naked fire, with the precaution of putting a certain
quantity of water into the distilling vessel along with it, to prevent
its suffering a greater heat than that of boiling water, all the
essential oil contained in that plant will rise together with that
water, and with the same degree of heat.
On this occasion it must be observed, that no essential oil can be
obtained from a plant after the _Spiritus Rector_ hath been drawn off;
which gives ground to think that the volatility of these oils is owing
to that spirit.
The heat of boiling water is also sufficient to separate from vegetable
matters the fat oils which they contain. That, however, is to be done
by the way of decoction only, and not by distillation: because, though
these oils will swim on water, yet they will not rise in vapours
without a greater degree of heat.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account