Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
I do not here speak of pure, vitrifiable, or refractory earths; of
mere metals and semi-metals; of pure acids; or even of their simplest
combinations, such as sulphur, vitriol, alum, sea-salt: of all these we
have said enough.
We are now to treat of bodies that are more complex, and therefore more
susceptible of decomposition. These bodies are compound masses, or
combinations of those above-mentioned; that is, metallic substances as
they are found in the bowels of the earth, united with several sorts
of sand, stones, earths, semi-metals, sulphur, _&c._ When the metallic
matter is combined with other matters, in such a proportion to the
rest that it may be separated from them with advantage and profit,
these compounds are called _Ores_; when the case is otherwise, they are
called _Pyrites_, and _Marcasites_; especially if sulphur or arsenic be
predominant therein, which often happens.
In order to analyse an ore, and get out of it the metal it contains,
the first step is to free it from a great deal of earth and stones,
which commonly adhere to it very slightly and superficially. This
is effected by pounding the ore, and then washing it in water; to
the bottom of which the metalline parts presently sink, as being the
heaviest, while the small particles of earth and stone remain suspended
some time longer.
Thus the metallic part is left combined with such matters only as are
most intimately complicated with it. These substances are most commonly
sulphur and arsenic. Now, as they are much more volatile than other
mineral matters, they may be dissipated in vapours, or the sulphur may
be consumed, by exposing the ore which contains them to a proper degree
of heat. If the sulphur and arsenic be desired by themselves, the fumes
thereof may be catched and collected in proper vessels and places. This
operation is called _Roasting_ an Ore.
The metal thus depurated is now fit to be exposed to a greater force of
fire, capable of melting it.
On this occasion the semi-metals and the imperfect metals require
the addition of some matter abounding in phlogiston, particularly
charcoal-dust; because these metallic substances lose their phlogiston
by the action of the fire, or of the fluxes joined with them, and
therefore without this precaution would never acquire either the
splendour or the ductility of a metal. By this means the metallic
substance is more accurately separated from the earthy and stony parts,
of which some portion always remains combined therewith till it is
brought to fusion. For, as we observed before, a metallic glass or calx
only will contract an union with such matters; a metal possessed of its
phlogiston and metalline form being utterly incapable thereof.
We took notice of the cause of this separation above, where we shewed
that a metal possessed of its phlogiston and metalline form will not
remain intimately united with any calcined or vitrified matter, not
even with its own calx or glass.
Public-domain text, read in full here on John Shaqi.
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