Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In order to decompose a copper ore, and to extract the copper it
contains, it is first of all to be freed from as many of its earthy,
stony, sulphureous, and arsenical parts, as is possible, by roasting
and washing; then what remains is to be mixed with a flux, compounded
of a fixed alkali and some inflammable matter; a little sea-salt is
to be put over all, and the whole melted by a strong fire. The salts
facilitate the fusion and scorification of the unmetallic matters, and
therewith form a slag, which being the lightest rises to the surface.
The metalline matters are collected below in the form of a shining
regulus of copper; which, however, is not usually fine copper, but
requires to be purified in the manner to be shewn in our second part.
In order to separate the copper from the unmetallic matters, it is
absolutely necessary to melt its ore along with inflammable substances
abounding in phlogiston. For, as this metal is not possessed of its
metalline form while it is in a mineral state, as it is destitute of
the true quantity of phlogiston, and, though it were not, would lose it
by the action of the fire, it would come to pass, that if its ore were
melted without the addition of any inflammable matter, the cupreous
earth or calx would be scorified and confounded with the unmetallic
matters; and as all metallic matters, except gold and silver, are
subject to this inconvenience as well as copper, the addition of an
inflammable substance, in fluxing all ores that contain them, is a
general rule that ought constantly to be observed.
_Of Iron Ores._
Iron is seldom found pure and malleable in the earth; yet it is much
seldomer found in the mineral state, properly so called, than any of
the other metals: for most iron ores are scarce any thing more than a
ferruginous earth mixed in different proportions with unmetallic earths
and stones. Some of them, however, contain also volatile minerals, such
as sulphur and arsenic; and therefore it is necessary to roast the iron
ores, like all others, before you attempt to extract the metal out of
them. That being done, they are to be smelted with a flux consisting of
fusible and inflammable matters, as the general rule directs.
Iron is the commonest of all metals: nay, it is so universally diffused
through the earth, that it is difficult to find any stone, earth, or
sand, that does not contain some of it; and therefore none of these are
usually considered and treated as iron ores, except such as contain a
great deal of that metal, and melt easily. The hematites, emery, yellow
pyrites, calamine, all contain a pretty considerable quantity of iron;
but no body attempts to extract it from them, because they are very
hard to melt.
Ferruginous earth being naturally of an orange colour, a stone or earth
may be judged to contain iron, if either naturally, or after roasting,
it appears to have one shade of yellow or red.
Public-domain text, read in full here on John Shaqi.
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