Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The eleventh column shews, that Lead has a greater affinity with Silver
than with Copper.
The twelfth, that Copper has a greater affinity with Mercury than with
Calamine.
The thirteenth, that Silver has a greater affinity with Lead than with
Copper.
The fourteenth contains the affinities of Iron. Regulus of Antimony
stands immediately underneath it, as being the Metallic substance which
has the greatest affinity with it. Silver, Copper, and Lead, are placed
together in the next square below, because the degrees of affinity
which those metals have with Iron are not exactly determined.
The same is to be said of the fifteenth column: Regulus of Antimony
stands at its head; Iron is immediately below it; and below the Iron
the same three metals occupy one square as before.
Lastly, the sixteenth column indicates that Water has a greater
affinity with Spirit of Wine than with Salts. By this general
expression must not be understood any Saline substance whatever; but
only the Neutral Salts, which Spirit of Wine frees from the water that
kept them in solution. Fixed Alkalis, on the contrary, as well as the
Mineral Acids, have a greater affinity than Spirit of Wine with water:
so that these Saline substances, being well dephlegmated, and mixed
with Spirit of Wine; imbibe the water it contains and rectify it.
To these might be added another short column, having Spirit of Wine at
its head: immediately below it should be the character of Water, and
below that the mark of Oil. This column would shew that the Spirit of
Wine has a greater affinity with Water than with Oils; because any Oily
matter whatever, that is dissolved in Spirit of Wine, may be actually
separated from it by the affusion of Water. This rule admits of no
exception but in one case; which is when the oily substance partakes
of the nature of soap, by having contracted an union with some saline
matter. But as this must be imputed wholly to that adventitious saline
matter being superadded to the oily substance, it is no just foundation
for an exception, and the affinity in question is nevertheless general.
We have now delivered every thing material that we had to say
concerning Mr. Geoffroy's Table of Affinities. It is, as we observed
before, of exceeding great service, as it collects into one view
the principal truths laid down in this Treatise. Indeed the most
advantageous way of using it is, not to delay consulting it till you
have read the book through, but to turn to it while you are reading, as
oft as any affinity between bodies is treated of; which it will imprint
more strongly on your mind, by representing it in a manner before your
eyes.
CHAP. XVIII.
_The_ THEORY _of_ CONSTRUCTING _the_ VESSELS _most commonly used in_
CHYMISTRY.
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