Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It is proper, therefore, now and then, to introduce a dish full of
hot water under the head which receives the fumes of the Sulphur. The
vapours that exhale from the water be-dew the inside of the head, and
procure the advantage we are speaking of.
The same thing may be effected several other ways: thus, the crucible
containing the Sulphur may be set on a foot placed in an earthen dish
with some water in it; which, however, must not rise above the foot;
for if it should reach the crucible, it might cool and fix the sulphur.
The dish thus prepared must be placed on a sand-bath hot enough to make
the water smoke continually; and over all is to be placed the head as
directed in the process.
The size and form of the vessel which immediately receives the
sulphureous fumes may also contribute to increase the quantity of the
Acid Spirit. A very large vessel, with a hole at bottom no wider than
is just sufficient to admit the vapours, is the properest for this
operation.
After the Sulphur has burnt for some time, it often happens that a sort
of skin or crust forms on its surface, which is not inflammable, but
gradually lessens the quantity and vigour of the flame as it increases
in thickness, and at last puts it quite out. This crust proceeds from
the impurities, and heterogeneous uninflammable particles contained in
the sulphur. Care must be taken to remove it with an iron wire as fast
as it forms.
Two quantities of sulphur may also be kept in two crucibles, and
heated alternately. That in which the Sulphur is hot and melted may be
substituted for the other in which the Sulphur is grown cold and fixed;
because cold Sulphur does not burn well.
The Spirit of Sulphur is at first pungent and volatile, because it
still retains a small portion of the Phlogiston: but that sulphureous
part flies off, especially if the bottle in which the Spirit is kept be
left for some time unstopped.
The Acid obtained from Sulphur appears by all chymical proofs perfectly
like that obtained from Vitriol: they differ in this only, that the
former is the purest; for the Acid obtained from Vitriol carries over
with it some metallic parts, as we observed before, which can never
happen to that obtained from Sulphur.
If linen rags dipped in a solution of Fixed Alkali be exposed to the
fumes of burning brimstone, the Spirit of Sulphur joins with the
Alkali, and therewith forms a Vitriolated Tartar. This Salt is known
to be formed when the rags grow stiff, and appear spangled with a vast
many glittering points, which are nothing but little crystals of the
Salt we are speaking of.
Public-domain text, read in full here on John Shaqi.
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