Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
There is moreover another advantage in not using the sand-bath; which
is, that if in the time of the operation you perceive the fire too
fierce, you can quickly check it, either by stopping close all the
apertures of the furnace, or by drawing out all or part of the lighted
coals. This inconvenience is not near so easily remedied when you use
the sand-bath; because when once heated it retains its heat very long
after the fire is quite extinguished.
PROCESS VII.
_To decompose Vitriolated Tartar by means of the Phlogiston; or to
compose Sulphur by combining the Vitriolic Acid with the Phlogiston._
Take equal parts of Vitriolated Tartar, and very dry Salt of Tartar,
separately reduced to powder; add an eighth part of their weight of
charcoal-dust; and mix the whole together very accurately. Throw this
mixture into a red-hot crucible, placed in a furnace filled with
burning coals. Cover it very close, and keep it very hot; till the
mixture melt, which may be known by uncovering the crucible from time
to time. There will then appear a blueish flame, accompanied with a
pungent smell of Sulphur.
Take the crucible out of the fire: dissolve its contents in hot water:
filter the solution through brown paper supported by a glass funnel:
drop into the filtered liquor by little and little any Acid whatever.
As you add the acid the liquor will grow more and more turbid, and let
fall a grey precipitate. Continue dropping in more Acid till the liquor
will yield no more precipitate. Filter it a second time, to separate it
from the precipitate: what remains on the filter is a true inflammable
Sulphur, which you may either melt or sublime into flowers.
_OBSERVATIONS._
All bodies that contain the Vitriolic Acid may contribute, as well
as Vitriolated Tartar, to the generation of Sulphur: so that all the
neutral salts in which this Acid is a principle, the Alums, Selenites,
Gypsums, Vitriols, may be substituted for it in this experiment. All
these matters, with the addition of charcoal-dust only, being fused
in a crucible, constantly produce Sulphur; because the Vitriolic Acid
having a greater affinity with the Phlogiston than with any thing
else, will quit its basis, whatever it be, to join with the Phlogiston
of the charcoal, and therewith form a Sulphur.
The fixed Alkali added thereto helps to promote the fusion of the
ingredients, which is necessary for effecting the desired combination.
It also serves to unite with the Sulphur, when formed; and thus makes
the combination called _Liver of Sulphur_, which prevents the Sulphur
from being consumed as soon as formed: for the fixed Alkalis, which are
incombustible, hinder Sulphur from burning so easily as it would do if
they were not joined with it. They may afterwards be separated from
each other, by the means of any Acid whatever.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account