Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It is easy to perceive why several adopters are required in this
experiment, and why a very small quantity of the mixture must be
introduced into the retort at once. The explosion, and the quantity of
air and vapours discharged on this occasion, would quickly burst the
vessels, if all these precautions were not attended to. This plainly
appears from the terrible effects of gun-powder, which is nothing but a
composition of Nitre, Sulphur, and Charcoal.
Nitre is also decomposed and takes fire by the means of Sulphur; but
the circumstances and the result differ widely from those produced
therewith by charcoal, or any other inflammable body.
Nitre deflagrates with Sulphur on account of the Phlogiston which the
latter contains. If one part of Sulphur be mixed with two or three
parts of Nitre, and the mixture thrown by little and little into a
red-hot crucible, upon every projection there arises a detonation
accompanied with a vivid flame.
The vapours discharged on this occasion have the mingled smell of
a Sulphureous Spirit and Spirit of Nitre; and if they be collected
by means of a tubulated retort, and such an apparatus of vessels as
was used in the preceding experiment, the liquor contained in the
recipients is found to be an actual mixture of the Acid of Sulphur, the
Sulphureous Spirit, and the Acid of Nitre; the first being in greater
quantity than the other two, and the second greater than the last.
Nor is the remainder after detonation a Fixed Alkali, as in the former
experiments; but a Neutral Salt, consisting of the Acid of Sulphur
combined with the Alkali of Nitre; a sort of Vitriolated Tartar known
in medicine by the name of _Sal Polychrestum_.
There are evidently two essential differences between this last
experiment and the preceding one. What remains after the deflagration
of Nitre with Sulphur is not a Fixed Alkali: and, moreover, the vapours
emitted in the operation are impregnated with a quantity of the Nitrous
Acid; which is not the case when Nitre is decomposed by any other
inflammable matter which contains no Vitriolic Acid.
The reason of these differences is naturally deducible from what hath
been already said concerning the properties of the Vitriolic and
Nitrous Acids. We have seen that by burning Sulphur its Acid is not
decomposed, but only separated from its Phlogiston. We also know,
that its Acid has a great affinity with Fixed Alkalis. These things
being granted, it follows that, as soon as the Nitrous Acid quits its
Alkaline basis, by deflagrating with the Phlogiston of the Sulphur, the
Acid of this very Sulphur, being set at liberty by that deflagration,
must unite with the Alkaline basis deserted by the Acid of Nitre, and
therewith form a Neutral Salt. Hence, instead of a Fixed Alkali, we
find at the end of the operation a sort of Vitriolated Tartar; the
Acids of Sulphur and of Vitriol being the same, as is evident from what
hath been above said concerning them.
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