Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the operation is over, you will find a red mass at the bottom of
the retort, cast, as it were, in a mould. This is a Neutral Salt of the
nature of Vitriolated Tartar, resulting from the union of the Acid of
the Vitriol with the Alkaline basis of the Nitre.
The ferruginous basis of the Vitriol, which is mixed with this salt,
gives it the red colour. To separate it therefrom, you must pulverise
it, dissolve it in boiling water, and filter the solution several times
through brown paper; because the ferruginous earth of the Vitriol is
so fine, that some of it will pass through the first time. When the
solution is very clear, and deposites no sediment, let it be set to
shoot, and it will yield crystals of Vitriolated Tartar; to which
Chymists have given the peculiar title of _Sal de duobus_.
In this _Caput mortuum_ we frequently find, besides the ferruginous
earth of Vitriol, a portion of Nitre and Vitriol not decomposed; either
because the two salts were not thoroughly mingled, or because the fire
was not raised high enough towards the end of the operation.
Nitre may also be decomposed, and its acid obtained, by the
interposition of any of the other Vitriols, Alums, Gypsums, Boles,
Clays; in short, by means of any compound in which the Vitriolic Acid
is found, provided it have not a Fixed Alkali for its basis.
The distillers of _Aqua fortis_, who make large quantities at a time,
and who use the least chargeable methods, do their business by the
means of earths impregnated with the Vitriolic Acid; such as Clays
and Boles. With these earths they accurately mix the Nitre from which
they intend to draw their Spirit: this mixture they put into large
oblong earthen pots, having a very short curved neck, which enters a
recipient of the same matter and form. These vessels they place in two
rows opposite to each other in long furnaces, and cover them over with
bricks cemented with Windsor-loam, which serves for a reverberatory:
then they light the fire in the furnace, making it at first very small,
only to warm the vessels; after which they throw in wood, and raise the
fire till the pots grow quite red-hot, in which degree they keep it up
till the distillation is entirely finished.
The Acid of Nitre may also be separated from its basis by means of the
pure Vitriolic Acid. For this purpose the Nitre from which you mean to
extract the Acid must be finely pulverized, put into a glass retort,
and a third of its weight of concentrated Oil of Vitriol poured on it:
the retort must be placed in a reverberating furnace, and a receiver,
like that used in the preceding operation, expeditiously applied.
As soon as the Oil of Vitriol touches the Nitre the mixture grows hot,
and copious red fumes begin to appear: some drops of the Acid come over
even before the fire is kindled in the furnace.
Public-domain text, read in full here on John Shaqi.
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