Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
These pyramidal crystals are only collections of small cubical crystals
concreted into this form. When they have acquired a certain magnitude
they fall to the bottom of the liquor. When they come to be in such
heaps as almost to reach the surface of the liquor, decant it from
them, and continue the evaporation till no more crystals of Sea-salt
will shoot.
_OBSERVATIONS._
The Acid of Sea-salt is scarce ever found, either in sea-water or in
the earth, otherwise than united with a fixed alkali of a particular
kind, which is its natural basis; and consequently it is in the form of
a Neutral Salt. This salt is plentifully dissolved in the waters of the
ocean, and when obtained therefrom bears the name of _Sea-salt_. It is
also found in the earth in vast crystalline masses, and is then called
_Sal-gem_: so that Sea-salt and Sal-gem are but one and the same sort
of salt, differing very little from each other, except as to the places
where they are found.
In the earth are also found springs and fountains, whose waters are
strong brines, a great deal of Sea-salt being dissolved in them. These
springs either rise directly from the sea, or run through some mines
of Sal-gem, of which they take up a quantity in their passage.
As the same, or at least nearly the same, quantity of Sea-salt will
continue dissolved in cold water as boiling water will take up, it
cannot shoot, as Nitre does, by the mere cooling of the water in which
it is dissolved: it crystallizes only by the means of evaporation,
which continually lessens the proportion of the water to the salt; so
that it is always capable of containing just so much the less Sea-salt
the more there is crystallized.
The brine should not boil after you perceive the pellicle of little
crystals beginning to form on its surface; for the calmness of the
liquor allows them to form more regularly, and become larger. Nor after
this should the evaporation be hurried on too fast; for a saline crust
would form on the liquor, which, by preventing the vapours from being
carried off, would obstruct the crystallization.
If the evaporation be continued after the liquor ceases to yield any
crystals of Sea-salt, other crystals will be obtained of an oblong
four-sided form, which have a bitter taste, and are almost always
moist. This sort of salt is known by the name of _Epsom Salt_, which
it owes to a salt spring in England, from the water of which it was
first extracted. This salt, or rather saline compound, is a congeries
of Glauber's salt and Sea-salt, in a manner confounded together, and
mixed with some of the Mother of Sea-salt, in which is contained a
kind of bituminous matter. These two Neutral Salts, which constitute
the Epsom Salt, may be easily separated from each other, by means of
crystallization only. Epsom Salt is purgative and bitter; and therefore
named _Sal Catharticum Amarum_, or bitter purging Salts.
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