Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
He begins the distillation with warming the retorts slowly, for about
an hour, by a gentle heat. When that time is elapsed he raises the fire
gradually, so that in half an hour more the coals begin to touch the
bottoms of the retorts. He continues throwing coals into the furnace by
little and little, till they rise half way the heighth of the retorts;
and in this he employs another half hour. Lastly, in the next half hour
he raises the coals above the bowls of the retorts.
Then the Phosphorus begins to ascend in clouds: on this he instantly
increases the heat of the fire as much as possible, filling the furnace
quite up with coals, and making the retorts very red. This degree of
fire causes the Phosphorus to distil in drops, which fall to the bottom
of the water. He keeps up this intense heat for an hour and half, at
the end of which the operation is finished; so that it lasts but four
hours and an half in all: nay, he further assures us, that an artist
well versed in managing the fire, may perform it in four hours only. In
the same manner he distils the second moiety of his mixture in three
other such retorts.
The advantage he finds in making use of several small retorts, instead
of a single large one, is, that the heat penetrates them with more
ease, and the operation is performed with less fire, and in less time.
He purifies and moulds his Phosphorus much in the same manner as M.
Hellot does. From the quantity of ingredients above-mentioned, he
obtains two ounces and a half of fine crystalline moulded Phosphorus.
M. Marggraff considering, as a consequence of the experiments above
related, that a highly concentrated Acid of Sea-salt contributes
greatly towards the formation of Phosphorus, proceeded to try several
other experiments, in which he employed that Acid in a state of
combination with other bases. He mixed, for instance, an ounce of _Luna
cornea_ with an ounce and half of putrefied and inspissated urine, and
from the mixture obtained a very beautiful Phosphorus.
In short, the several experiments mentioned having thoroughly persuaded
him that the Acid of Sea-salt, provided it were highly concentrated,
would combine with the Phlogiston as readily as the Vitriolic Acid
does, he resolved to try whether he could not make Phosphorus with
matters containing that Acid and the Phlogiston, without making use of
any urine.
Public-domain text, read in full here on John Shaqi.
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