Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Mercury hath a greater affinity with the Marine than with the Nitrous
Acid. The affinity which Mercury hath with the Marine Acid is also
greater than that of Gold with the Marine Acid; for unless this Acid
be associated either with the Nitrous Acid, or at least with a certain
proportion of Phlogiston, it will not dissolve Gold. Hence it comes,
that when a solution of Mercury in the Nitrous Acid is dropped into a
solution of Gold in _aqua regis_, the Mercury unites with the Acid of
Sea-salt, which is an ingredient in the _aqua regis_: but the Marine
Acid cannot on this occasion join the Mercury, without deserting the
Gold and the Nitrous Acid with which it was united; and then the Gold,
which cannot be kept in solution by the Nitrous Acid alone, is forced
to quit its solvent and precipitate. The liquor, therefore, that now
floats over the Gold thus precipitated, must contain Mercury united
with the Acid of Sea-salt: and in fact it yields a true Corrosive
Sublimate, which is known to be a combination of Mercury with the
Marine Acid.
Mercury dissolved in Spirit of Nitre is employed to procure the
precipitation we are speaking of; because metallic substances, when so
comminuted by an Acid, are much fitter for such experiments than when
they are in a concrete form.
Gold precipitated in this manner by a metallic substance doth not
fulminate.
PROCESS III.
_To dissolve Gold by Liver of Sulphur._
Mix together equal parts of common Brimstone, and a very strong Fixed
Alkali; for instance, Nitre fixed by Charcoal. Put them in a crucible,
and melt the mixture, stirring it from time to time with a small rod.
There is no occasion to make the fire very brisk; because the Sulphur
facilitates the fusion of the Fixed Alkali. Some sulphureous vapours
will rise from the crucible; the two substances will mix intimately
together, and form a reddish compound. Then throw into the crucible
some little pieces of Gold beat into thin plates, so that the whole do
not exceed in weight one third part of the Liver of Sulphur: raise the
fire a little. As soon as the Liver of Sulphur is perfectly melted, it
will begin to dissolve the Gold with ebullition; and will even emit
some flashes of fire. In the space of a few minutes the Gold will be
entirely dissolved, especially if it was cut and flatted into small
thin leaves.
_OBSERVATIONS._
The process here delivered is taken from M. Stahl. The design of that
ingenious Chymist's inquiry was to discover how Moses could burn the
golden calf, which the Israelites had set up and worshipped while he
was on the mount; how he could afterwards reduce that calf to powder,
throw it into the water which the people used, and make all who had
apostatized drink thereof, as related in the Book of Exodus.
Public-domain text, read in full here on John Shaqi.
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