Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Hence it appears that there may be several different sorts of Black
Copper. Iron, Lead, Tin, Bismuth, and the reguline part of Antimony,
are almost always combined with the ores of Copper, in a multitude of
different proportions; and all these substances, being reduced by the
black flux in the operation, mix and precipitate with the Copper. If
the ore contain any Gold or Silver, as is pretty often the case, these
two metals also are confounded with the rest in the precipitation, and
become part of the Black Copper.
Pyritose, sulphureous, and arsenical Copper ores may be fused, in order
to get rid of the grosser heterogeneous parts, without previously
roasting them: but in this case no alkaline flux must be mixed with the
ore; because the Alkali in combination with the Sulphur would produce
a Liver of Sulphur, and so dissolve the metalline part; by which means
all would be confounded together, and no Regulus, or very little, be
precipitated. On this occasion therefore nothing must be added to
promote the fusion, but some tender fusile glass, together with a small
quantity of borax.
This first fusion may also be performed amidst the coals, by casting
the ore upon them in the furnace, without using a crucible; and then an
earthen vessel, thoroughly heated, or even made red-hot, must be placed
under the grate of the fire-place, to receive the metal as it runs from
the ore.
The Regulus obtained by this means is much more impure and brittle
than Black Copper, because it contains moreover a large quantity of
Sulphur and Arsenic; as these volatile substances have not time to
evaporate during the short space requisite to melt the ore, and as they
cannot be carried off by the action of the fire after the ore is once
melted, whatever time be allowed for that purpose. However, some part
thereof is dissipated; and the Iron which is in pyritose ores, having a
much greater affinity than Copper, and indeed than any other metallic
substance, with Sulphur and Arsenic, absorbs another part thereof, and
separates it from the Regulus.
This Regulus, it is plain, still contains all the same parts that were
in the ore, but in different proportions; there being more Copper,
combined with less Sulphur, Arsenic, and unmetallic earth, which have
been either dissipated or turned to slag. Therefore, if you would make
it like Black Copper, you must pound it, roast it over and over, to
free it from its Sulphur and Arsenic, and then melt it with the black
flux.
If this Regulus contain much Iron, it will be adviseable to melt it
once or twice more, before all the Sulphur and Arsenic are separated
from it by roasting; for as the Iron, by uniting with these volatile
substances, separates them from the Copper, with which they have not so
great an affinity; so also the Sulphur and Arsenic, by uniting with the
Iron, help in their turn to separate it from the Copper.
PROCESS II.
_To purify Black Copper, and render it malleable._
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account