Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
As Copper calcines with great difficulty, this operation is extremely
tedious: nay, though Copper hath stood thus exposed to the fire
for several days and nights, and seems perfectly calcined, yet it
frequently happens that, when you try afterwards to melt it, some of
it resumes the form of Copper: a proof that all the Copper had not
lost its phlogiston. Copper is much more expeditiously deprived of its
phlogiston by calcining it in a crucible with Nitre.
The calx of Copper perfectly calcined is with great difficulty brought
to fusion: yet, in the focus of a large burning-glass, it melts and
turns to a reddish and almost opaque glass.
By the process here delivered, you may likewise calcine all other
metalline substances, which do not melt till they are thoroughly
red-hot. As to those which melt before they grow red, they are easily
enough calcined, even while they are in fusion.
PROCESS IV.
_To resuscitate the Calx of Copper, and reduce it to Copper, by
restoring its Phlogiston._
Mix the Calx of Copper with thrice as much of the black flux; put the
mixture into a good crucible, so as to fill two thirds thereof, and
over it put a layer of Sea-salt a finger thick. Cover the crucible, and
set it in a melting furnace; heat it gradually, and keep it moderately
red till the decrepitation of the Sea-salt be over. Then raise the fire
considerably by means of a good pair of perpetual bellows; satisfy
yourself that the matter is in perfect fusion, by dipping into the
crucible an iron wire; continue the fire in this degree for half a
quarter of an hour. When the crucible is cold, you will find at its
bottom a button of very fine Copper, which will easily separate from
the saline scoria at top.
_OBSERVATIONS._
What hath been said before on the smelting of Copper ores may be
applied to this process, as being the very same. The observations there
added should therefore be consulted on this occasion.
PROCESS V.
_To dissolve Copper in the Mineral Acids._
On a sand-bath, in a very gentle heat, set a matrass containing some
Copper filings; pour on them twice their weight of Oil of Vitriol. That
Acid will presently attack the Copper. Vapours will rise, and issue
out of the neck of the matrass. A vast number of bubbles will ascend
from the surface of the metal to the top of the liquor, and the liquor
will acquire a beautiful blue colour. When the Copper is dissolved, put
in a little and a little more, till you perceive the Acid no longer
acts upon it. Then decant the liquor, and let it stand quiet in a cool
place. In a short time great numbers of beautiful blue crystals will
shoot in it. These crystals are called _Vitriol of Copper_, or _Blue
Vitriol_. They dissolve easily in water.
_OBSERVATIONS._
The Vitriolic Acid perfectly dissolves Copper, which is also soluble in
all the Acids, and even in many other menstruums.
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