Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In smelting-houses Iron ore is fused amidst charcoal, the phlogiston
of which combines with the martial earth, and gives it the metalline
form. The Iron thus melted runs down to the bottom of the furnace, from
whence it is let out into large moulds, in which it takes the shape of
oblong blocks, called _Pigs_ of Iron. This Iron is still very impure,
and quite unmalleable. Its want of ductility after the first melting
arises partly from hence, that, notwithstanding the previous roasting
which the ore underwent, there still remains, after this first fusion,
a considerable quantity of Sulphur or Arsenic combined with the metal.
A certain quantity of quick-lime, or of stones that will burn to lime,
is frequently mixed with Iron ore on putting it into the smelting
furnace. The lime being an absorbent earth, very apt to unite with
Sulphur and Arsenic, is of use to separate those minerals from the Iron.
It is also of use to mix some such matters with the ore, when the
stones or earths which naturally accompany it are very fusible; for, as
the Iron is of difficult fusion, it may happen that the earthy matters
mixed with the Iron shall melt as easily as the metal, or perhaps
more easily. In such a case there is no separation of the earthy
from the metalline part, both of which melt and precipitate together
promiscuously; now quick-lime, being extremely refractory, serves on
this occasion to check the melting of those matters which are too
fusible.
Yet quick-lime, notwithstanding its refractory quality, may sometimes
be of use as a flux for Iron. This is the case when the ore happens to
be combined with substances which, being united with lime, render it
fusible: such are all arsenical matters, and even some earthy matters,
which being combined with quick-lime make a fusible compound.
When the ore of an Iron mine is found difficult to reduce, it is
usually neglected even though it be rich: because Iron being very
common, people chuse to work those mines only whose ores are smelted
with the most ease, and require the least consumption of wood.
Yet refractory ores are not to be altogether rejected, when another
Iron ore of a different quality is found near them. For it often
happens, that two several Iron ores, which being worked separately
are very difficult to manage, and yield at last but bad metal, become
very tractable, and yield excellent Iron, when smelted together: and
accordingly such mixtures are often made at Iron-works.
Public-domain text, read in full here on John Shaqi.
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