Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the matter is in fusion keep stirring it from time to time, that
all the parts thereof may be equally acted on by the air and the fire.
On the surface of the melted Iron _scoriæ_ will be formed, which must
be taken off as they appear. At the same time you will see a great many
sparkles darted up from the surface of the metal, which will form a
sort of fiery shower. By degrees, as the Iron grows purer, the number
of these sparkles diminishes, though they never vanish entirely. When
but few sparkles appear, remove the coals which cover the Iron, and
let the slag run out of the vessel; whereupon the metal will grow
solid in a moment. Take it out while it is still red-hot, and give
it a few strokes with a hammer, to try if it be ductile. If it be
not yet malleable, repeat the operation a second time, in the same
manner as before. Lastly, when it is thus sufficiently purified by the
fire, work it for a long time on the anvil, extending it different
ways, and making it red-hot as often as there is occasion. Iron thus
brought to the necessary degree of ductility, so as to yield to the
hammer, and suffer itself to be extended every way, either hot or cold,
without breaking to bits, or even cracking in the least, is very good
and very pure. If it cannot be brought to this degree by the method
here prescribed, it is a proof that the ore from which this Iron was
extracted ought to be mixed with other ores; but it frequently requires
a great number of trials to obtain an exact knowledge of the quality
and proportion of those other ores with which it is to be mixed.
_OBSERVATIONS._
The brittleness and shortness of Pig-iron arises from the heterogeneous
parts which it contains, and which could not be separated from it
by the first fusion. These extraneous matters are usually Sulphur,
Arsenic, and unmetallic earth, and also a ferruginous earth; but
such as could not be combined with the phlogiston as it ought to be,
in order to have the properties of a metal, and must therefore be
considered as heterogeneous, with respect to the other well-conditioned
martial particles.
The Pig-iron, by undergoing repeated fusions, is freed from those
heterogeneous matters; those which are volatile, such as Sulphur and
Arsenic, being dissipated, and the unmetallic matters being scorified.
As to the ferruginous earth, which did not at first acquire the
metalline form, it becomes true Iron at last; because, among the coals
with which it is encompassed, it meets with a sufficient quantity of
phlogiston to reduce it to metal. Charcoal is also necessary on this
occasion, that it may continually furnish phlogiston to the Iron, which
would otherways be converted into a calx.
Hammering the red-hot Iron, after each fusion, serves to force out from
amongst the martial parts such earthy matters as may happen to remain
there, and so bring into closer contact the metalline parts which were
separated before by the interposition of those heterogeneous matters.
PROCESS III.
Public-domain text, read in full here on John Shaqi.
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