Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If two or three parts of Oil of Vitriol be poured on one part of Tin,
and if the vessel in which the mixture is made be exposed to such a
degree of heat as to evaporate all the moisture, there will remain
a tenacious matter sticking to the sides of the vessel. If water
be poured on this matter, and it be then exposed a second time to
the fire, it will dissolve entirely, excepting a small portion of
a glutinous substance, which also may be dissolved in fresh Oil of
Vitriol.
The Acid of Sea-salt may be combined with Tin by the following process.
Mix perfectly, by trituration in a marble mortar, an amalgam of two
ounces of fine Tin, and two ounces and a half of Quick-silver, with
as much Corrosive Sublimate. As soon as the mixture is completed, put
it into a glass retort, and distil with the same precautions as we
directed to be used in preparing concentrated and smoking Acids. There
will first come over into the receiver some drops of a limpid liquor,
which will be soon followed by an elastic spirit that will issue out
with impetuosity. At last some flowers, and a saline tenacious matter,
will rise into the neck of the retort. Then stop your distillation,
and pour into a glass bottle the liquor you will find in the receiver.
This liquor continually exhales a considerable quantity of dense, white
fumes, as long as it is allowed to have a free communication with the
air.
The product of this distillation is a combination of the Acid of
Sea-salt with Tin. As the affinity of Tin with this Acid is greater
than that of Mercury, the Acid contained in the Corrosive Sublimate
quits the Mercury, wherewith it was united, to join the Tin; which it
volatilizes so as to make it rise with itself in a limpid form. We make
use of the amalgam of Tin with Quick-silver, because we are thereby
enabled to mix the Corrosive Sublimate perfectly therewith, as the
success of the operation requires it should be.
In this experiment the Tin is volatilized, and the Acid of Sea-salt,
which is exceedingly concentrated, flies off incessantly in the form
of white vapours. This compound is known in Chymistry by the name of
_Smoking Liquor of Libavius_; a name derived from its quality, and from
its Inventor. Tin dissolved by Acids is easily separated from them by
Alkalis. It always precipitates in the form of a white calx.
CHAP. VI.
_Of_ LEAD.
PROCESS I.
_To extract Lead from its Ore._
Having roasted your Lead ore reduce it to a fine powder; mix it with
twice its weight of the black flux, and one fourth of its weight of
clean iron filings and borax; put the whole into a crucible capable of
containing at least thrice as much; over all put Sea-salt four fingers
thick; cover the crucible; lute the juncture; dry the whole with a
gentle heat, and set it in a melting furnace.
Make the crucible moderately red: you will hear the Sea-salt
decrepitate, and after the decrepitation a small hissing in the
crucible. Keep up the same degree of fire till that be over.
Public-domain text, read in full here on John Shaqi.
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