Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Notwithstanding all the precautions that can be used to prevent the
reduction from taking place too hastily, and so occasioning the
effusion of the matter, it often happens that, on raising the fire in
order to bring the mixture into fusion, the hissing suddenly begins
again, and is very loud. In that case all the apertures of the furnace
must immediately be shut close, in order to choak and suffocate the
fire: for, if this be neglected, the matter in the crucible will swell
up, make its way through the luting of the juncture, nay, push up the
cover, and run over. This accident is to be apprehended during the
first five or six minutes after you raise the fire in order to melt
the mixture. This effusion of the matter is accompanied with a dull
flame, a thick, grey and yellow smoke, and a noise like that of some
boiling liquor. When you observe these several phenomena you may be
sure the matter is run out of the crucible, either in the manner above
described, or by making its way through some cracks in the vessel, and
consequently that the operation is spoiled.
Moreover, this event infallibly follows whenever a bit of coal happens
to fall into the crucible; and this is one reason why it is necessary
to cover it.
You may be certain that the operation hath succeeded if the scoria be
smooth when cold, and have not in part escaped through the lute; if
the Lead be not dispersed in globules through the whole mass of the
matter contained in the crucible, but is, on the contrary, collected at
the bottom, in the form of a solid Regulus, not very shining, but of a
blueish cast, and ductile. Moreover, the scoria ought, in the present
case, to be hard and black, and should not appear full of holes like a
sieve, except only in that part which was contiguous to the Salt.
Here it is proper to observe, that the Sea-salt doth not mix with the
scoria, but floats upon it. After the operation it is black; which
colour it gets, no doubt, from the charred parts of the flux. The
absence of these signs shews the operation to have miscarried.
When the ore to be smelted is pyritose and refractory, it may be
roasted at first with a much stronger degree of fire than is used for
ores that are fusible; because the martial earth, and the unmetallic
earth, which are always mixed in pyritose matters, hinder it from
growing readily soft in the fire. Besides, such an ore requires a
greater quantity of the black flux and of borax to be mixed with it,
and a higher degree of fire to fuse it.
It is generally needless to mix iron filings with this sort of ore;
because the martial earth, with which pyritose matters are always
accompanied, is reduced during the operation by the help of the black
flux, which for that purpose is mixed with it in a large proportion,
and furnishes a quantity of iron sufficient to absorb the heterogeneous
minerals mixed with the Lead.
Public-domain text, read in full here on John Shaqi.
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