Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Sometimes it is only mixed with earthy and stony matters that contain
no Sulphur; but, as this metallic substance is never destitute of its
phlogiston, it then has its metalline form and properties. When it is
found in this condition, nothing is more easy than to separate it from
those heterogeneous matters. For that purpose no more is requisite than
to distil the whole with a fire strong enough to raise the Mercury in
vapours. This mineral is volatile; the earthy and stony matters are
fixed; and a certain degree of heat will effect a complete separation
of what is volatile from what is fixed.
This is not the case when Mercury is combined with Sulphur: for this
latter mineral is volatile as well as Mercury; and the compound
resulting from the union of them both is also volatile: so that if
Cinabar were exposed to the fire in close vessels, as it must be to
save the Mercury, it would be sublimed in substance, without being
decomposed at all.
In order therefore to separate these two substances from each other,
we must have recourse to the interposition of some third, which hath a
greater affinity with one of them than the other hath, and no affinity
with that other.
Iron hath all the conditions requisite for this purpose; seeing it
hath, as may be seen in the Table, a much greater affinity with Sulphur
than Mercury hath, and is incapable of contracting any union with
Mercury.
Iron, however, is not the only substance that may be employed on this
occasion: Fixed Alkalis, Absorbent earths, Copper, Lead, Silver,
Regulus of Antimony, have all, as well as Iron, a greater affinity
than Mercury with Sulphur. Nay, several of these substances, namely,
the saline and earthy Alkalis, as well as Regulus of Antimony, cannot
contract any union with Mercury: the rest, to wit, Copper, Lead, and
Silver, are indeed capable of amalgamating with Mercury; but then the
union which these metals contract with the Sulphur prevents it; and
even though they should unite with this metallic substance, the degree
of heat to which the whole mixture is exposed would soon carry up the
Mercury, and separate it with ease from those fixed substances.
In this distillation the same cautions must be observed as in all
others: that is, the vessels must be slowly heated, especially if a
glass retort be used; the fire must be raised by degrees, and a much
stronger one applied at last than at first. This operation particularly
requires a very strong degree of fire, when there is but a small
quantity of Mercury left.
After the operation there remains in the retort a compound of Iron and
Sulphur, which may easily be converted into a _crocus_, by calcining it
and burning away the Sulphur.
If a Fixed Alkali be employed, a Liver of Sulphur will be found in the
retort after the distillation.
If the Cinabar from which you extract the Mercury be good, you will
generally obtain seven eighths of its weight in Quick-silver.
Public-domain text, read in full here on John Shaqi.
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