Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
But as the chymical examination of this subject hath long been
neglected, the existence of a saline substance in Lime hath been long
doubtful. Mr. du Fay, author of some excellent chymical experiments,
was one of the first who obtained a salt from Lime, by lixiviating
it with a great deal of water, which he afterwards evaporated. But
the quantity of salt he obtained by that means was very small; nor
was it of an alkaline nature, as one would think it should have been,
considering the properties of Lime. Mr. du Fay did not carry his
experiments on this subject any further, probably for want of time; nor
did he determine of what nature the salt was.
Mr. Malouin had the curiosity to examine this salt of Lime, and
soon found that it was nothing else but what was above called
_Cremor Calcis_. He found, moreover, that, by mixing a fixed alkali
with lime-water, a vitriolated tartar was formed; that, by mixing
therewith an alkali like the basis of sea-salt, a Glauber's salt was
produced; and, lastly, by combining lime with a substance abounding
in phlogiston, he obtained a true sulphur. These very ingenious
experiments prove to a demonstration, that the vitriolic acid
constitutes the salt of Lime: for, as hath been shewn, no other acid is
capable of forming such combinations. On the other hand, Mr. Malouin,
having forced the vitriolic acid of this salt to combine with a
phlogiston, found its basis to be earthy, and analogous to that of the
selenites: whence he concluded, that the salt of Lime is a true neutral
salt, of the same kind as the selenites. Mr. Malouin tells us he found
several other salts in Lime. But as none of them was a fixed alkali,
and as all the saline properties of Lime have an affinity with those of
that kind of salt, there is great reason to think that all those salts
are foreign to Lime, and that their union with it is merely accidental.
Public-domain text, read in full here on John Shaqi.
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