Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
We shall begin with mentioning the experiments which prove Metallic
Substances to consist of a vitrifiable earth united with the
phlogiston. The first is this: if they be calcined in such a manner
as to have no communication with any inflammable matter, they will be
spoiled of all their properties, and reduced to an earth or calx, that
has neither the splendour nor the ductility of a metal, and in a strong
fire turns to an actual glass, instead of flowing like a metal.
The second is, that the calx or the glass resulting from a metal thus
decomposed, recovers all its metalline properties by being fused in
immediate contact with an inflammable substance, capable of restoring
the phlogiston of which calcination had deprived it.
On this occasion we must observe, that Chymists have not yet been
able, by adding the phlogiston, to give the properties of metals to
all sorts of vitrifiable earths indiscriminately; but to such only as
originally made a part of some metallic body. For example, a compound
cannot be made with the phlogiston and sand that shall have the least
resemblance of a metal: and this is what seems to point out the reality
of a third principle, as necessary to form the metalline combination.
This principle may probably remain united with the vitrifiable earth
of a metallic substance, when reduced to a glass; whence it follows,
that such vitrified metals require only the addition of a phlogiston to
enable them to appear again in their pristine form.
It may be inferred from another experiment, that the calx and the glass
of a metal are not its pure vitrifiable earth, properly so called: for
by repeated or long-continued calcinations, such a calx or glass may
be rendered incapable of ever resuming the metalline form, in whatever
manner the phlogiston be afterwards applied to it; so that by this
means it is brought into the condition of a pure vitrifiable earth,
absolutely free from any mixture. Those Chymists who patronize the
Mercurial earth, produce many other proofs of the existence of that
principle in Metallic Substances; but they would be misplaced in an
elementary treatise like this.
When by adding the phlogiston to a metallic glass we restore it to the
form of a metal, we are said to _reduce_, _resuscitate_, or _revivify_
that metal.
Metallic Substances are of different kinds, and are divided into
_Metals_ and _Semi-metals_.
Those are called Metals which, besides their metalline splendour
and appearance, are also malleable; that is, have the property of
stretching under the hammer, and by that means of being wrought into
different forms without breaking.
Those which have only the metalline splendour and appearance, without
malleability, are called Semi-metals.
Metals are also further subdivided into two sorts; _viz._ _Perfect_ and
_Imperfect_ Metals.
The Perfect Metals are those which suffer no damage or change whatever
by the most violent and most lasting action of fire.
Public-domain text, read in full here on John Shaqi.
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