Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The Imperfect Metals are those which by the force of fire, may be
deprived of their phlogiston, and consequently of their metalline form.
When but a moderate degree of fire is employed to deprive a Metal of
its phlogiston, the metal is said to be _calcined_; and then it appears
in the form of a powdered earth, which is called a _Calx_: and this
metalline calx being exposed to a more violent degree of fire melts and
turns to glass.
Metallic Substances have an affinity with acids: but not equally with
all; that is, every Metallic Substance is not capable of uniting and
joining with every acid.
When an acid unites with a Metallic Substance there commonly arises
an ebullition, attended with a kind of hissing noise and fuming
exhalations. By degrees, as the union becomes more perfect, the
particles of the metal combining with the acid become invisible: this
is termed _Dissolution_; and when a metalline mass thus appears in an
acid, the metal is said to be _dissolved_ by that acid. It is proper
to observe, that acids act upon Metalline Substances, in one respect,
just as they do upon alkalis and absorbent earths: for an acid cannot
take up above such a certain proportion thereof as is sufficient to
saturate it, to destroy several of its properties, and weaken others.
For example, when an acid is combined with a metal to the point of
saturation, it loses its taste, does not turn the blue colour of a
vegetable red, and its affinity with water is considerably impaired. On
the other hand, Metalline Substances, which when pure are incapable of
uniting with water, by being joined with an acid acquire the property
of dissolving in water. These combinations of Metalline Substances with
acids form different sorts of neutral salts; some of which have the
property of shooting into crystals, while others have it not: most of
them, when thoroughly dried, attract the moisture of the air.
The affinity which Metalline Substances have with acids is less than
that which absorbent earths and fixed alkalis have with the same
acids; so that all metalline salts may be decompounded by one of these
substances, which will unite with the acid, and precipitate the metal.
Metalline Substances thus separated from an acid solvent are called
_Magisteries_ and _Precipitates_ of metals. None of these precipitates,
except those of the perfect metals, retain the metalline form: most of
their phlogiston hath been destroyed by the solution and precipitation,
and must be restored before they can recover their properties. In
short, they are nearly in the same state with Metalline Substances
deprived of their phlogiston by calcination; and accordingly such a
precipitate is called a _Calx_.
A metalline calx prepared in this manner loses a greater or a less
portion of its phlogiston, the more or less effectually and thoroughly
the Metalline Substance, of which it made a part, was dissolved by the
acid.
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