Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
3. The small portion of vitrified matter, which was formed on the arm
that supported the Gold in Mr. Homberg's experiment, may have come
either from the arm itself, or rather from some heterogeneous particles
contained in the Gold; for it is almost impossible to have it perfectly
pure.
4. Neither Mr. Homberg, nor any that have repeated his experiment, ever
reduced this pretended glass of Gold by restoring its Phlogiston, as is
done with other metallic glasses.
5. To render the experiment decisive, the whole mass of Gold employed
ought to have been vitrified; which was not the case.
Nevertheless, I do not pretend that this metal is in its own nature
absolutely indestructible, and unvitrifiable: but there is reason to
think that no body hath hitherto found the means of producing those
effects on it, probably for want of a sufficient degree of fire; at
least the point is very doubtful.
Gold cannot be dissolved by any pure acid: but if the acid of nitre be
mixed with the acid of sea-salt, there results a compound acid liquor,
with which it has so great an affinity that it is capable of being
perfectly dissolved thereby. The Chymists have called this solvent
_Aqua Regis_, on account of its being the only acid that can dissolve
Gold, which they consider as the King of Metals. The solution of gold
is of a beautiful orange colour.
If Gold dissolved in _aqua regis_ be precipitated by an alkali or an
absorbent earth, the precipitate gently dried, and then exposed to a
certain degree of heat, is instantly dispersed into the air, with a
most violent explosion and noise: Gold thus precipitated is therefore
called _Aurum Fulminans_. But if the precipitated Gold be carefully
washed in plenty of water, so as to clear it of all the adhering saline
particles, it will not fulminate, but may be melted in a crucible
without any additament, and will then appear in its usual form. The
acid of vitriol being poured on _aurum fulminans_ likewise deprives it
of its fulminating quality.
Gold does not begin to flow till it be red-hot like a live coal. Though
it be the most malleable and most ductile of all metals, it has the
singular property of losing its ductility more easily than any of them:
even the fumes of charcoal are sufficient to deprive it thereof, if
they come in contact with it while it is in fusion.
The malleability of this metal, and indeed of all the rest, is also
considerably diminished by exposing it suddenly to cold when it is
red-hot; for example, by quenching it in water, or even barely exposing
it to the cold air.
The way to restore ductility to gold, when lost by its coming in
contact with the vapour of coals, and in general to any metal rendered
less malleable by being suddenly cooled, is to heat it again, to keep
it red hot a considerable time, and then to let it cool very slowly
and gradually; this operation frequently repeated will by degrees much
increase the malleability of a metal.
Public-domain text, read in full here on John Shaqi.
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