Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
In order to remedy this inconvenience, and free _aqua fortis_ from
the vitriolic or marine acid with which it is tainted, Silver must
be dissolved therein: by degrees as the metal dissolves, those
heterogeneous acids lay hold of it, and precipitate with it in the form
of a white powder, as we observed before. This precipitate being wholly
fallen, the liquor grows clear; after which, if it be found capable of
dissolving more silver, without turning milky, it may be depended on as
a perfectly pure _aqua fortis_. Then filtre it, dissolve more Silver
in it, as long as it will take up any, and you will have a solution
of Silver in a very pure _aqua fortis_. By means of this solution may
other _aqua fortis_ be purified: for pour a few drops thereof into
a very impure _aqua fortis_, and immediately the vitriolic or marine
acid, with which that _aqua fortis_ is contaminated, will join the
Silver and fall therewith to the bottom. When the solution of Silver,
prepared as above, does not in the least affect the transparency of
the _aqua fortis_, it is then very pure, and fit for the purposes of
Quartation.
This operation of purifying _aqua fortis_ by a solution of Silver is
called the _Precipitation_ of _Aqua Fortis_, and _aqua fortis_ thus
purified is called _Precipitated Aqua Fortis_.
When Silver is dissolved in _aqua fortis_ it may be separated
therefrom, as hath been shewn, by absorbent earths and fixed alkalis.
We shall see by and by that there are other means of effecting this:
but whatever way it be separated from its solvent it recovers its
metalline form, as Gold does, by being simply fused without any
additament.
SECTION III.
_Of_ COPPER.
Of all the imperfect metals Copper comes the nearest to Gold and
Silver. Its natural colour is a deep-red yellow. It resists a very
violent degree of fire for a considerable time; but losing its
phlogiston at last, it changes its metalline form for that of a calx,
or a pure reddish earth. This calx is hardly, if at all, reducible to
glass, without the addition of something to promote its fusion; all
that the fiercest heat can do being only to render it soft. Copper,
even while it retains its metalline form, and is very pure, requires a
considerable degree of fire to melt it, and does not begin to flow till
long after it is red-hot. When in fusion, it communicates a greenish
colour to the flame of the coals.
Public-domain text, read in full here on John Shaqi.
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